(a) Interpretation: The mechanism and major organic product for the given reaction is to be drawn. Concept introduction: The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

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Answer 1

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

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H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.

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Y= - 0.039 (14.01) + 0.7949

Answer 2

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

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Answer 3

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Answer 6

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Answer 7

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

(a) Interpretation: The mechanism and major organic product for the given reaction is to be drawn. Concept introduction: The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

(a) Interpretation: The mechanism and major organic product for the given reaction is to be drawn. Concept introduction: The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

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Chapter 21 Solutions

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.