(a) Interpretation: The major product of the given reaction is to be predicted. Concept introduction: The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows: Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 5

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 6

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 7

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

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Chapter 21 Solutions