Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed Concept introduction: Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different. Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

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Answer 1

Question

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

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Answer 3

Question

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

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Answer 4

Question

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

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Answer 5

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

Answer 6

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

Answer 7

Chapter 21, Problem 21.26P

Interpretation Introduction

Interpretation:

Synthetic approach to synthesize the given compound without using ester of the form given below via Claisen-Condensation is to proposed

Concept introduction:

Caisen condensation can be self Claisen condensation or cross Claisen condensation. In self condensation, two precursors are identical while in cross, they are different.

Here, retrosynthesis of the product suggests that it is a product of cross Claisen condensation. In cross condensation, one precursor should be an ester or ketone that cannot form enolate, and another which can form enolate.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

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Chapter 21 Solutions