EBK PHYSICAL CHEMISTRY
2nd Edition
ISBN: 8220100477560
Author: Ball
Publisher: Cengage Learning US
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Textbook Question
Chapter 21, Problem 21.46E
What is the coordination number in the cesium chloride cubic structure?
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Identify the structure of the PTH derivative generated after two rounds of Edman degradation.
Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the
drawing window.
Data selected from the NIST
WebBook,
https://webbook.nist.gov/chemistry/
m/z
Relative intensity
31
0.5
30
26
29
22
28
100
27
33
26
23
15
4
• You do not have to consider stereochemistry.
You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
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n
?
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for this question.
Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 98.1106.
Exact Masses of the Most Abundant Isotope of
Selected Elements
Isotope Natural abundance (%) Exact mass
1H
99.985
1.008
12C
98.90
12.000
14N
99.63
14.003
160
99.76
15.995
Molecular formula
(In the order CHNO, with no subscripts)
Chapter 21 Solutions
EBK PHYSICAL CHEMISTRY
Ch. 21 - Prob. 21.1ECh. 21 - Boron nitride, BN, is a very hard material, harder...Ch. 21 - Prob. 21.3ECh. 21 - Prob. 21.4ECh. 21 - Figure 21.35 shows a unit cell of diamond....Ch. 21 - Prob. 21.6ECh. 21 - How many different unit cells can a crystal have...Ch. 21 - Prob. 21.8ECh. 21 - Prob. 21.9ECh. 21 - Prob. 21.10E
Ch. 21 - Prob. 21.11ECh. 21 - Prob. 21.12ECh. 21 - Prob. 21.13ECh. 21 - Prob. 21.14ECh. 21 - Prob. 21.15ECh. 21 - Prob. 21.16ECh. 21 - Prob. 21.17ECh. 21 - Prob. 21.18ECh. 21 - Prob. 21.19ECh. 21 - Prob. 21.20ECh. 21 - Prob. 21.21ECh. 21 - Prob. 21.22ECh. 21 - Prob. 21.23ECh. 21 - Prob. 21.24ECh. 21 - Prob. 21.25ECh. 21 - Prob. 21.26ECh. 21 - Prob. 21.27ECh. 21 - Prob. 21.28ECh. 21 - For a simple cubic lattice, what is the ratio of...Ch. 21 - Prob. 21.30ECh. 21 - Prob. 21.31ECh. 21 - Consider Figure 21.21. If the lower rightmost...Ch. 21 - Prob. 21.33ECh. 21 - The aluminum-nickel alloy AlNi has a simple cubic...Ch. 21 - Prob. 21.35ECh. 21 - The first two signals from a powdered sample has X...Ch. 21 - Prob. 21.37ECh. 21 - Prob. 21.38ECh. 21 - Prob. 21.39ECh. 21 - Prob. 21.40ECh. 21 - Prob. 21.41ECh. 21 - Prob. 21.42ECh. 21 - Prob. 21.43ECh. 21 - Prob. 21.44ECh. 21 - Prob. 21.45ECh. 21 - What is the coordination number in the cesium...Ch. 21 - Prob. 21.47ECh. 21 - Which solid phase that is, which allotrope of...Ch. 21 - Prob. 21.49ECh. 21 - Prob. 21.50ECh. 21 - Write Born-Haber cycles showing the relationship...Ch. 21 - Prob. 21.52ECh. 21 - Prob. 21.53ECh. 21 - Prob. 21.54ECh. 21 - The lattice energy for potassium iodide, KI, is...Ch. 21 - Prob. 21.56ECh. 21 - Prob. 21.57ECh. 21 - Prob. 21.58ECh. 21 - Prob. 21.59ECh. 21 - Prob. 21.60ECh. 21 - Prob. 21.61ECh. 21 - Prob. 21.62ECh. 21 - Prob. 21.63ECh. 21 - Prob. 21.64E
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- PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS!!! PLEASE I UNDERSTAND THE BASICS BUT THIS IS AN EXCEPTION THAT EVEN THE INTERNET CANT HELP!!!! THIS IS THE THIRD TIME I'VE SENT THOSE QUESTIONS SO PLEASE DONT RESEND THE SAME STUFF, ITS NOT HELPING ME!!! I ALSO ALREADY TRIED TO DRAW THE MECHANISM MYSELF, SO IF ITS RIGHT PLEASE TELL ME OR TELL ME WHAT I HAVE TO CHANGE!!! First image: I have to SHOW (DRAWING) the mechanism (with arows and structures of molecules) NOT WORDS PLEASE! of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary Second image: I have to show the mechanism (IMAGE) (with arrows and structures of the molecules) NOT WORDS PLEASE !! for the reaction on the left, where the alcohol A is added fast in one portion HOMEWORK, NOT EXAM!! ALL DETAILS ARE IN THE IMAGES PLEASE LOOK AT THE IMAGES, DONT LOOK AT THE AI GENERATED TEXT!!!arrow_forwardWrite the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 85.0899. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)arrow_forwardUse the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 59 3.0 58 64 43 100 15 23 • You do not have to consider stereochemistry. •You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. + n[] 85 // ? CH4 Previous Nextarrow_forward
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