Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 21, Problem 21.38AP
Interpretation Introduction

(a)

Interpretation:

The structure for the compound B is to be predicted. The explanation for the corresponding answer is to be stated.

Concept introduction:

Amides are the organic compounds that are formed by a combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the conversion of B into C is to be predicted.

Concept introduction:

Amides are the organic compounds that are formed by combination of carboxylic acids and amine. Amides are hydrolyzed either in acidic or basic media to yield carboxylic acids and amine or ammonium ion and carboxylate anions.

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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.  Will the following reaction make a molecule with a new C – C bond as its major product:  Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
Please do not use AI.  AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at.  All of these compounds would be produced (I think).  In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason.  Please explain why some of these produce less yield than others.
Please answer the question and provide detailed explanations.
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