Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 21, Problem 21.35E
Interpretation Introduction
Interpretation:
The type of cubic crystal and the unit cell parameter is to be predicted.
Concept introduction:
A unit cell of the crystal is the three-dimensional arrangement of the atoms present in the crystal. The unit cell is the smallest and simplest unit of the crystal which on repetition forms an entire crystal. Unit cell can be a cubic unit cell or hexagonal unit cell. The classification of a unit cell depends on the lattice site occupied by the atoms.
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In the video, we looked at the absorbance of a certain substance and how it varies
depending on what wavelength of light we are looking at. Below is a similar scan of a
different substance. What color BEST describes how this substance will appear?
Absorbance (AU)
Violet
Blue
Green
Orange
1.2
1.0-
0.8-
0.6-
0.4-
0.2
0.0
450
500
550
600
650
700
Wavelength (nm)
violet
indigo
blue
green
yellow orange
red
Red
O Cannot tell from this information
In the above graph, what causes -450 nm wavelength of light to have a higher
absorbance than light with a -550 nm wavelength? Check all that are true.
The distance the light travels is different
The different data points are for different substances
The concentration is different at different times in the experiment
Epsilon (molar absortivity) is different at different wavelengths
5. a. Data were collected for Trial 1 to determine the molar mass of a nonvolatile solid solute when dissolved in cyclo-
hexane. Complete the table for the analysis (See Report Sheet). Record calculated values with the correct number
of significant figures.
B. Freezing Point of Cyclohexane plus
Calculation Zone
Unknown Solute
2. Mass of cyclohexane (g)
10.14
Part C.4
3. Mass of added solute (g)
0.255
C. Calculations
1. k; for cyclohexane (°C⚫ kg/mol)
20.0
2. Freezing point change, AT, (°C)
3.04
Part C.6
3. Mass of cyclohexane in solution (kg)
4. Moles of solute, total (mol)
Show calculation.
5. Mass of solute in solution, total (g)
6. Molar mass of solute (g/mol)
Show calculation.
Chapter 21 Solutions
Physical Chemistry
Ch. 21 - Prob. 21.1ECh. 21 - Boron nitride, BN, is a very hard material, harder...Ch. 21 - Prob. 21.3ECh. 21 - Prob. 21.4ECh. 21 - Figure 21.35 shows a unit cell of diamond....Ch. 21 - Prob. 21.6ECh. 21 - How many different unit cells can a crystal have...Ch. 21 - Prob. 21.8ECh. 21 - Prob. 21.9ECh. 21 - Prob. 21.10E
Ch. 21 - Prob. 21.11ECh. 21 - Prob. 21.12ECh. 21 - Prob. 21.13ECh. 21 - Prob. 21.14ECh. 21 - Prob. 21.15ECh. 21 - Prob. 21.16ECh. 21 - Prob. 21.17ECh. 21 - Prob. 21.18ECh. 21 - Prob. 21.19ECh. 21 - Prob. 21.20ECh. 21 - Prob. 21.21ECh. 21 - Prob. 21.22ECh. 21 - Prob. 21.23ECh. 21 - Prob. 21.24ECh. 21 - Prob. 21.25ECh. 21 - Prob. 21.26ECh. 21 - Prob. 21.27ECh. 21 - Prob. 21.28ECh. 21 - For a simple cubic lattice, what is the ratio of...Ch. 21 - Prob. 21.30ECh. 21 - Prob. 21.31ECh. 21 - Consider Figure 21.21. If the lower rightmost...Ch. 21 - Prob. 21.33ECh. 21 - The aluminum-nickel alloy AlNi has a simple cubic...Ch. 21 - Prob. 21.35ECh. 21 - The first two signals from a powdered sample has X...Ch. 21 - Prob. 21.37ECh. 21 - Prob. 21.38ECh. 21 - Prob. 21.39ECh. 21 - Prob. 21.40ECh. 21 - Prob. 21.41ECh. 21 - Prob. 21.42ECh. 21 - Prob. 21.43ECh. 21 - Prob. 21.44ECh. 21 - Prob. 21.45ECh. 21 - What is the coordination number in the cesium...Ch. 21 - Prob. 21.47ECh. 21 - Which solid phase that is, which allotrope of...Ch. 21 - Prob. 21.49ECh. 21 - Prob. 21.50ECh. 21 - Write Born-Haber cycles showing the relationship...Ch. 21 - Prob. 21.52ECh. 21 - Prob. 21.53ECh. 21 - Prob. 21.54ECh. 21 - The lattice energy for potassium iodide, KI, is...Ch. 21 - Prob. 21.56ECh. 21 - Prob. 21.57ECh. 21 - Prob. 21.58ECh. 21 - Prob. 21.59ECh. 21 - Prob. 21.60ECh. 21 - Prob. 21.61ECh. 21 - Prob. 21.62ECh. 21 - Prob. 21.63ECh. 21 - Prob. 21.64E
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