Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 21, Problem 21.54E
Interpretation Introduction
Interpretation:
The lattice energy of
Concept introduction:
The amount of energy released when one formula unit moles of oppositely charged gaseous ions binds together to form a crystal is known as the lattice energy. The value of lattice energy is negative. It is used as a measure for stability of a crystal.
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Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.
Chapter 21 Solutions
Physical Chemistry
Ch. 21 - Prob. 21.1ECh. 21 - Boron nitride, BN, is a very hard material, harder...Ch. 21 - Prob. 21.3ECh. 21 - Prob. 21.4ECh. 21 - Figure 21.35 shows a unit cell of diamond....Ch. 21 - Prob. 21.6ECh. 21 - How many different unit cells can a crystal have...Ch. 21 - Prob. 21.8ECh. 21 - Prob. 21.9ECh. 21 - Prob. 21.10E
Ch. 21 - Prob. 21.11ECh. 21 - Prob. 21.12ECh. 21 - Prob. 21.13ECh. 21 - Prob. 21.14ECh. 21 - Prob. 21.15ECh. 21 - Prob. 21.16ECh. 21 - Prob. 21.17ECh. 21 - Prob. 21.18ECh. 21 - Prob. 21.19ECh. 21 - Prob. 21.20ECh. 21 - Prob. 21.21ECh. 21 - Prob. 21.22ECh. 21 - Prob. 21.23ECh. 21 - Prob. 21.24ECh. 21 - Prob. 21.25ECh. 21 - Prob. 21.26ECh. 21 - Prob. 21.27ECh. 21 - Prob. 21.28ECh. 21 - For a simple cubic lattice, what is the ratio of...Ch. 21 - Prob. 21.30ECh. 21 - Prob. 21.31ECh. 21 - Consider Figure 21.21. If the lower rightmost...Ch. 21 - Prob. 21.33ECh. 21 - The aluminum-nickel alloy AlNi has a simple cubic...Ch. 21 - Prob. 21.35ECh. 21 - The first two signals from a powdered sample has X...Ch. 21 - Prob. 21.37ECh. 21 - Prob. 21.38ECh. 21 - Prob. 21.39ECh. 21 - Prob. 21.40ECh. 21 - Prob. 21.41ECh. 21 - Prob. 21.42ECh. 21 - Prob. 21.43ECh. 21 - Prob. 21.44ECh. 21 - Prob. 21.45ECh. 21 - What is the coordination number in the cesium...Ch. 21 - Prob. 21.47ECh. 21 - Which solid phase that is, which allotrope of...Ch. 21 - Prob. 21.49ECh. 21 - Prob. 21.50ECh. 21 - Write Born-Haber cycles showing the relationship...Ch. 21 - Prob. 21.52ECh. 21 - Prob. 21.53ECh. 21 - Prob. 21.54ECh. 21 - The lattice energy for potassium iodide, KI, is...Ch. 21 - Prob. 21.56ECh. 21 - Prob. 21.57ECh. 21 - Prob. 21.58ECh. 21 - Prob. 21.59ECh. 21 - Prob. 21.60ECh. 21 - Prob. 21.61ECh. 21 - Prob. 21.62ECh. 21 - Prob. 21.63ECh. 21 - Prob. 21.64E
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