General Chemistry: Principles and Modern Applications, Loose Leaf Version (11th Edition)
11th Edition
ISBN: 9780133897319
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 21, Problem 15E
Interpretation Introduction
Interpretation:
Whether the following process obeys the principal of conservation of charge or not should be determined. Explain.
In sea water, the starting material is
Concept introduction:
According to the principal of conservation of charges, the total charge of a given isolated system will never change. This means that the net electric charge which is equal to the subtraction of quantity of positive charge and the quantity of negative charge in this universe always remains conserved.
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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?
b. What is the purpose of the Na2SO4?
c. What equipment would you use to “concentrate [a solution] under reduced pressure”?
Chapter 21 Solutions
General Chemistry: Principles and Modern Applications, Loose Leaf Version (11th Edition)
Ch. 21 - Prob. 1ECh. 21 - Use information from the chapter to write chemical...Ch. 21 - Prob. 3ECh. 21 - Describe two methods for determining the identity...Ch. 21 - Arrange the following compounds in the expected...Ch. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - A lithium battery used in a cardiac pacemaker has...Ch. 21 - Prob. 9ECh. 21 - Prob. 10E
Ch. 21 - The standard Gibbs energies of formation, rG , for...Ch. 21 - Prob. 12ECh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Write chemical equations for the reactions you...Ch. 21 - Without performing detailed calculations, indicate...Ch. 21 - Prob. 20ECh. 21 - With respect to decomposition to MO(s) and SO2(g)...Ch. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Methane and sulfur vapor react to form carbon...Ch. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Write plausible chemical equations for the (a)...Ch. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Aqueous tin(II) ion, Sn2+(aq) , is a good reducing...Ch. 21 - Would you expect the reaction of Sn(s) and Cl2(g)...Ch. 21 - Prob. 54ECh. 21 - Prob. 55IAECh. 21 - The following series of observations is made: (1)...Ch. 21 - Prob. 57IAECh. 21 - Prob. 58IAECh. 21 - Prob. 59IAECh. 21 - Prob. 60IAECh. 21 - Lithium superoxide, LiO2(s) , has never been...Ch. 21 - Prob. 62IAECh. 21 - Prob. 63IAECh. 21 - Prob. 64IAECh. 21 - Use data from Appendix D (Table D-2) to calculate...Ch. 21 - Prob. 66IAECh. 21 - A particular water sample contains 56.9 ppm SO42-...Ch. 21 - An aluminum production cell of the type pictured...Ch. 21 - Prob. 69IAECh. 21 - Prob. 70IAECh. 21 - Prob. 71IAECh. 21 - Prob. 72IAECh. 21 - Prob. 73IAECh. 21 - Prob. 74IAECh. 21 - Prob. 75IAECh. 21 - Would you expect the lattice energy of MgS(s) to...Ch. 21 - Prob. 77IAECh. 21 - Prob. 78FPCh. 21 - Prob. 79FPCh. 21 - Prob. 80SAECh. 21 - Briefly describe each of the following ideas,...Ch. 21 - Explain the important distinction between each...Ch. 21 - Prob. 83SAECh. 21 - Prob. 84SAECh. 21 - Predict the products of the following reactions:...Ch. 21 - A chemist knows that aluminum is more reactive...Ch. 21 - Listed are several pairs of substances. For some...Ch. 21 - Prob. 88SAECh. 21 - Prob. 89SAECh. 21 - Prob. 90SAECh. 21 - Prob. 91SAECh. 21 - Prob. 92SAECh. 21 - Prob. 93SAECh. 21 - Prob. 94SAECh. 21 - Prob. 95SAE
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