Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 21, Problem 13P
Interpretation Introduction

Interpretation:

The oxidation state of metals and thetotal number of valence electrons in metals forming complexes are to be determined. Whether the metals in the complexes are saturated or unsaturated is also to be stated.

Concept Introduction:

Oxidation state of a metal in a complex is the charge on the metal that would be there even if all the anionic ligands and counter ions were removed.

Total valence electrons of a metal in a complex is obtained by the following formula:

Total number of valence electrons of metal in complex = dn + electrons donated by ligands

Here, dn is d-electrons in metal.

The number of electrons required to complete the octet in transition metals is 18. As along with s and p orbitals, they have d orbitals too in their valence shell. Together the three orbitals can acquire 18 electrons in the valence shell, 2 in s, 6 in p, and 10 in d orbitals.

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esc Write the systematic name of each organic molecule: structure CH3 CH3-C=CH2 CH3-CH2-C-CH2-CH3 CH-CH3 CH3 ☐ ☐ ☐ CI-CH-CH=CH2 Explanation Check F1 F2 name 80 F3 F4 F5 F6 A 7 ! 2 # 3 4 % 5 6 & 7 Q W E R Y FT 2025 Mc
Two reactants X and Z are required to convert the compound CH3-CH2-CH2Br to the compound CH3-CH2-CH=P(C6H5)3. State reactants X and Z.
2. Write a reasonable mechanism that converts the reactants into the products. Avoid issues A-U from the previous page. You can use any number of steps (it does not have to be a one-step mechanism). Do not use any other chemicals (solvents, acids, bases, etc.) in your mechanism. 2 2 H ΗΘ
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