Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 21, Problem 12PP

Practice Problem 21.12

What products would form when each of the following compounds is treated with ( P C y 3 ) 2 C l 2 R u = C H P h , one of Grubbs’ catalysts?

(a)

Chapter 21, Problem 12PP, Practice Problem 21.12 What products would form when each of the following compounds is treated with , example  1

(b)

Chapter 21, Problem 12PP, Practice Problem 21.12 What products would form when each of the following compounds is treated with , example  2

(c)

Chapter 21, Problem 12PP, Practice Problem 21.12 What products would form when each of the following compounds is treated with , example  3

(d)

Chapter 21, Problem 12PP, Practice Problem 21.12 What products would form when each of the following compounds is treated with , example  4

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of N2 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm ☑ 5 00. 18 Ar

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