Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 20.2, Problem 3P
Interpretation Introduction

Interpretation:

Structure for an optically inactive fat that, when hydrolysed under acidic condition gives glycerol with one equivalent lauric acid and two equivalents of stearic acid has to be identified.

Concept Introduction:

Triglycerides are compounds in which the three OH groups of glycerol are esterified with fatty acids.

Triglycerides that are solids or semisolids at room temperature are fats and liquid triglycerides are oils.

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4. The ester you drew in Question #1 has a melting point range of 32-35 °C. The methyl ester of mono-unsaturated palmitoleic acid (IUPAC name: hexadec-9enoic acid) has a considerably lower melting point range: -0.5-+0.5 °C. a) Explain what it means for a fatty acid to the "mono-unsaturated." b) Illustrate your explanation by drawing the structure of the methyl ester of octadec-11-enoic acid. (Be sure to draw the geometric stereoisomer that is commonly found in nature.)
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