The constitutional isomers should be identified for the given molecules by using its structure. Concept introduction: Stereoisomerism : The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces. Constitutional Isomers : The compounds that have the same molecular formula but different in their chemical structures. To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

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Answer 1

Question

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 2

Question

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

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Answer 3

Question

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

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Answer 4

Question

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

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Answer 5

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

Answer 6

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

Answer 7

Chapter 20, Problem 74PP

(a)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (a) by using its nomenclature method.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (b) by using its nomenclature method.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The constitutional isomers should be identified for the given molecules by using its structure.

Concept introduction:

Stereoisomerism: The stereoisomers are molecules that differ only in the arrangement of bonds in three dimensional spaces.

Constitutional Isomers: The compounds that have the same molecular formula but different in their chemical structures.

To identify: The constitutional isomer for the given molecule (c) by using its nomenclature method.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 20.2 - Prob. 2ATS Ch. 20.2 - Prob. 4ATS Ch. 20.3 - Prob. 5CC Ch. 20.4 - Prob. 6CC Ch. 20.5 - Prob. 7CC Ch. 20.5 - Prob. 2LTS Ch. 20.5 - Prob. 8PTS Ch. 20.5 - Prob. 9ATS Ch. 20.5 - Prob. 10ATS Ch. 20.5 - Prob. 11CC

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Chapter 20 Solutions