Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 20, Problem 68P
Interpretation Introduction

Interpretation:

A structure for the disaccharide is to be proposed.

Concept Introduction:

The disaccharides formed from the monosaccharide units that are connected with each other through the glycosidic bonds.  Glycosidic bonds are the type of covalent bonds.  The condensation reactions are also involved in the formation of disaccharides.  The elimination of water molecules takes place during the condensation reactions.

Monosaccharide units are made from the biomolecules that comprise carbon, oxygen and hydrogen atoms.  These molecules cannot be broken into the simpler compounds.  The numbers of isomers are obtained from biomolecules due to the chiral nature of carbon atoms.

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• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
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Organic Chemistry (8th Edition)

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