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Concept explainers
a)
Interpretation:
The other monosaccharides that are reduced to the alditol obtained from the reduction of given monosaccharides are to be stated.
Concept Introduction:
Monosaccharides:
Monosaccharides are made from the
A numbers of isomers are obtained from biomolecules due to the chiral nature of carbon atoms.
Chiral molecules are those molecules that consist of different groups or atoms around the central atom. Isomers are those compounds that have same molecular formula but different arrangement of atoms, groups or substituents in a compound.
b)
Interpretation:
The monosaccharides that are reduced to two alditols and out of two, the alditol obtained from the reduction of the given monosaccharides are to be stated.
Concept Introduction:
Monosaccharides:
Monosaccharides are made from the biomolecules that comprise carbon, oxygen and hydrogen atoms. These molecules cannot be broken into the simpler compounds.
The disaccharides and polysaccharides are further formed from monosaccharide units. A numbers of isomers are obtained from biomolecules due to the chiral nature of carbon atoms.
Chiral molecules are those molecules that consist of different groups or atoms around the central atom. Isomers are those compounds that have same molecular formula but different arrangement of atoms, groups or substituents in a compound.
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Chapter 20 Solutions
Organic Chemistry (8th Edition)
- Nonearrow_forwardNonearrow_forwardIn the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.arrow_forward
- 1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forwardWrite the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward
- 3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward
- 2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward
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