The structures of two five-membered-ring lactones are to be drawn. Concept Introduction: The aldaric acid of D-glucose forms two five membered-ring lactones. Aldaric acid, also known as saccharic acid is a poly hydroxy dicarboxylic acid that is formally produced by the oxidation of aldose at both terminals. Aldaric acids are synthesized by the process of oxidation of aldose with nitric acid. These are also called sugar acids. In these acids terminal hydroxyl and carbonyl groups of the sugars have been replaced by terminal carboxylic acids and are characterized by the formula COOH − ( CHOH ) n − COOH . Here, n is the number of carbon units present in the chain other than terminal carbons. Lactones are cyclic compounds. These are formed by intramolecular esterification of the corresponding Saccharide units.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 59P

Interpretation Introduction

Interpretation:

The structures of two five-membered-ring lactones are to be drawn.

Concept Introduction:

The aldaric acid of D-glucose forms two five membered-ring lactones.

Aldaric acid, also known as saccharic acid is a poly hydroxy dicarboxylic acid that is formally produced by the oxidation of aldose at both terminals. Aldaric acids are synthesized by the process of oxidation of aldose with nitric acid. These are also called sugar acids.

In these acids terminal hydroxyl and carbonyl groups of the sugars have been replaced by terminal carboxylic acids and are characterized by the formula COOH−(CHOH)n−COOH. Here, n is the number of carbon units present in the chain other than terminal carbons.

Lactones are cyclic compounds. These are formed by intramolecular esterification of the corresponding Saccharide units.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

How many chiral carbons are present in the structural formula for the open-chain form of d-mannose? Draw the structure of the six-member-ring form of this molecule.

In an aqueous solution, d-glucose exists in equilibrium with two six-membered ring compounds. Draw the structures of these compounds.

Suppose the hydrogens on the OH groups in glucose were replaced with methyl groups, CH3. Would you expect the water solubility of the resulting molecule to be higher than, lower than, or about the same as glucose?

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 59P

Interpretation Introduction

Interpretation:

The structures of two five-membered-ring lactones are to be drawn.

Concept Introduction:

The aldaric acid of D-glucose forms two five membered-ring lactones.

Aldaric acid, also known as saccharic acid is a poly hydroxy dicarboxylic acid that is formally produced by the oxidation of aldose at both terminals. Aldaric acids are synthesized by the process of oxidation of aldose with nitric acid. These are also called sugar acids.

In these acids terminal hydroxyl and carbonyl groups of the sugars have been replaced by terminal carboxylic acids and are characterized by the formula COOH−(CHOH)n−COOH. Here, n is the number of carbon units present in the chain other than terminal carbons.

Lactones are cyclic compounds. These are formed by intramolecular esterification of the corresponding Saccharide units.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 59P

Interpretation Introduction

Interpretation:

The structures of two five-membered-ring lactones are to be drawn.

Concept Introduction:

The aldaric acid of D-glucose forms two five membered-ring lactones.

Aldaric acid, also known as saccharic acid is a poly hydroxy dicarboxylic acid that is formally produced by the oxidation of aldose at both terminals. Aldaric acids are synthesized by the process of oxidation of aldose with nitric acid. These are also called sugar acids.

In these acids terminal hydroxyl and carbonyl groups of the sugars have been replaced by terminal carboxylic acids and are characterized by the formula COOH−(CHOH)n−COOH. Here, n is the number of carbon units present in the chain other than terminal carbons.

Lactones are cyclic compounds. These are formed by intramolecular esterification of the corresponding Saccharide units.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 20, Problem 59P

Interpretation Introduction