The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated. Concept Introduction: An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Question

ii) Molecular ion peak :the peak corresponding to the intact molecule (with a positive charge) What would the base peak and Molecular ion peaks when isobutane is subjected to Mass spectrometry? Draw the structures and write the molecular weights of the fragments. Circle most stable cation a) tert-butyl cation b) Isopropyl cation c) Ethyl cation. d) Methyl cation 6. What does a loss of 15 represent in Mass spectrum? a fragment of the molecule with a mass of 15 atomic mass units has been lost during the ionization Process 7. Write the isotopes and their % abundance of isotopes of i) Cl

Answer 1

Question

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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ii) Molecular ion peak :the peak corresponding to the intact molecule (with a positive charge) What would the base peak and Molecular ion peaks when isobutane is subjected to Mass spectrometry? Draw the structures and write the molecular weights of the fragments. Circle most stable cation a) tert-butyl cation b) Isopropyl cation c) Ethyl cation. d) Methyl cation 6. What does a loss of 15 represent in Mass spectrum? a fragment of the molecule with a mass of 15 atomic mass units has been lost during the ionization Process 7. Write the isotopes and their % abundance of isotopes of i) Cl

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Answer 2

Question

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 3

Question

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 4

Question

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 5

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 6

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 7

Chapter 20, Problem 39P

a)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-glucose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 8

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 9

b)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-galactose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 10

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 11

c)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-ribose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 12

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 13

d)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-xylose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 14

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 15

e)

Interpretation Introduction

Interpretation:

The configuration of each of the asymmetric centers in the Fisher projection of D-sorbose is to be stated.

Concept Introduction:

An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached asymmetric carbon atoms are arranged according to their configuration in Fisher projection. The enantiomers of a chiral compound can be named the help of right hand and left hand configuration.

In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 16

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Answer 27

Ch. 20.1 - Prob. 1P Ch. 20.2 - Prob. 2P Ch. 20.2 - Prob. 3P Ch. 20.3 - Prob. 4P Ch. 20.3 - Prob. 5P Ch. 20.3 - Prob. 6P Ch. 20.4 - Prob. 7P Ch. 20.4 - Prob. 8P Ch. 20.5 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains the configuration of each of the asymmetric centers in the Fisher projection of D-glucose.

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