Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 20, Problem 37E
MTBE, Methyl tert -butyl ether, CH3OC(CH3)3, is used as an oxygen source in oxygenated gasolines. MTBE is manufactured by reacting 2-methy1propeue with methanol.
(a) Using Lewis structures, write the Chemical equation representing the reaction.
(b) What volume of methanol, density 0.7915 g/mL, is required to produce exactly 1000 kg of MTBE, assuming a 100% yield?
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Propane, C3H8, is a hydrocarbon that is commonly used as a fuel.(a) Write a balanced equation for the complete combustion of propane gas.(b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint:use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.)(c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH°f of propane given that ΔH°f of H2O(l) = −285.8 kJ/mol and ΔH°f of CO2(g) = −393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.
(i) Write the name and draw the structure of a saturated hydrocarbon with four carbon atoms.
TRUE OR FALSE
(a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions.
(b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom.
(c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups.
(d) There are two alcohols with the molecular formula C3H8O.
(e) There are three amines with the molecular formula C3H9N.
(f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group.
(g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid.
(h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°.
(i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O.
(j) The molecular formula of the smallest carboxylic…
Chapter 20 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 20 - Write the chemical formula and Lewis structure of...Ch. 20 - What is the difference between the hybridization...Ch. 20 - On a microscopic level, how does the reaction of...Ch. 20 - On a microscopic level, how does the reaction of...Ch. 20 - Explain why unbranched alkenes can form geometric...Ch. 20 - Explain why these two molecules are not isomers:Ch. 20 - Explain why these two molecules are not isomers:Ch. 20 - How does the carbon-atom hybridization change when...Ch. 20 - Write the Lewis structure and molecular formula...Ch. 20 - Write the chemical formula, condensed formula, and...
Ch. 20 - Give the complete IUPAC name for each of the...Ch. 20 - Give the complete IUPAC name for each of the...Ch. 20 - Butane is used as a fuel in disposable lighters....Ch. 20 - Write Lewis structures and name the five...Ch. 20 - Write Lewis structures for the Cis -trans isomers...Ch. 20 - Write structures for the three isomers of the...Ch. 20 - Isooctane is the common name of the isomer of...Ch. 20 - Write Lewis structures and IUPAC names for the...Ch. 20 - Write Lewis structures and IUPAC names for all...Ch. 20 - Name and write the structures of all isomers of...Ch. 20 - Write the structures for all the isomers of the...Ch. 20 - Write Lewis structures and describe the molecular...Ch. 20 - Benzene is one of the compounds used as an octane...Ch. 20 - Teflon is prepared by the polymerization of...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - What mass of 2-bromopropane could be prepared from...Ch. 20 - Acetylene is a very weak acid; however, it will...Ch. 20 - Ethylene can be produced by the pyrolysis of...Ch. 20 - Why do the compounds hexane, hexanol, and hexane...Ch. 20 - Write condensed formulas and provide IUPAC names...Ch. 20 - Give the complete IUPAC name for each of the...Ch. 20 - Give the complete IUPAC name and the common name...Ch. 20 - Write the condensed structures of both isomers...Ch. 20 - Write the condensed structures of all isomers with...Ch. 20 - Draw the condensed formulas for each of the...Ch. 20 - MTBE, Methyl tert -butyl ether, CH3OC(CH3)3, is...Ch. 20 - Write two complete balanced equations for each of...Ch. 20 - Write two complete balanced equations for each of...Ch. 20 - Order the following molecules from least to most...Ch. 20 - Predict the products of oxidizing the molecules...Ch. 20 - Predict the products of reducing the following...Ch. 20 - Explain why it is not possible to possible a...Ch. 20 - How does hybridization of the substituted carbon...Ch. 20 - Fatty acids are carboxylic acids that have long...Ch. 20 - Write a condensed structural formula, such as...Ch. 20 - Write a condensed structural formula, such as...Ch. 20 - The foul odor of rancid butter is caused by...Ch. 20 - Write the two-resonance structures for the acetate...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - Write two complete balanced equations for each of...Ch. 20 - Yields in organic reactions are sometimes low....Ch. 20 - Alcohols A, B and C all have the composition C4H...Ch. 20 - Write the Lewis structures of both isomers with...Ch. 20 - What is the molecular structure about the nitrogen...Ch. 20 - Write the two resonance structures for the...Ch. 20 - Draw Lewis structures for pyridine and its...Ch. 20 - Write the Lewis structures of all isomers with the...Ch. 20 - Write two complete balanced equations for the...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - Identify any carbon atoms that change...Ch. 20 - Identify any carbon atoms that change...Ch. 20 - Identify any carbon atoms that change...
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