Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 20, Problem 2E
What is the difference between the hybridization of carbon atoms' valence orbitals in saturated and
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 20 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 20 - Write the chemical formula and Lewis structure of...Ch. 20 - What is the difference between the hybridization...Ch. 20 - On a microscopic level, how does the reaction of...Ch. 20 - On a microscopic level, how does the reaction of...Ch. 20 - Explain why unbranched alkenes can form geometric...Ch. 20 - Explain why these two molecules are not isomers:Ch. 20 - Explain why these two molecules are not isomers:Ch. 20 - How does the carbon-atom hybridization change when...Ch. 20 - Write the Lewis structure and molecular formula...Ch. 20 - Write the chemical formula, condensed formula, and...
Ch. 20 - Give the complete IUPAC name for each of the...Ch. 20 - Give the complete IUPAC name for each of the...Ch. 20 - Butane is used as a fuel in disposable lighters....Ch. 20 - Write Lewis structures and name the five...Ch. 20 - Write Lewis structures for the Cis -trans isomers...Ch. 20 - Write structures for the three isomers of the...Ch. 20 - Isooctane is the common name of the isomer of...Ch. 20 - Write Lewis structures and IUPAC names for the...Ch. 20 - Write Lewis structures and IUPAC names for all...Ch. 20 - Name and write the structures of all isomers of...Ch. 20 - Write the structures for all the isomers of the...Ch. 20 - Write Lewis structures and describe the molecular...Ch. 20 - Benzene is one of the compounds used as an octane...Ch. 20 - Teflon is prepared by the polymerization of...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - What mass of 2-bromopropane could be prepared from...Ch. 20 - Acetylene is a very weak acid; however, it will...Ch. 20 - Ethylene can be produced by the pyrolysis of...Ch. 20 - Why do the compounds hexane, hexanol, and hexane...Ch. 20 - Write condensed formulas and provide IUPAC names...Ch. 20 - Give the complete IUPAC name for each of the...Ch. 20 - Give the complete IUPAC name and the common name...Ch. 20 - Write the condensed structures of both isomers...Ch. 20 - Write the condensed structures of all isomers with...Ch. 20 - Draw the condensed formulas for each of the...Ch. 20 - MTBE, Methyl tert -butyl ether, CH3OC(CH3)3, is...Ch. 20 - Write two complete balanced equations for each of...Ch. 20 - Write two complete balanced equations for each of...Ch. 20 - Order the following molecules from least to most...Ch. 20 - Predict the products of oxidizing the molecules...Ch. 20 - Predict the products of reducing the following...Ch. 20 - Explain why it is not possible to possible a...Ch. 20 - How does hybridization of the substituted carbon...Ch. 20 - Fatty acids are carboxylic acids that have long...Ch. 20 - Write a condensed structural formula, such as...Ch. 20 - Write a condensed structural formula, such as...Ch. 20 - The foul odor of rancid butter is caused by...Ch. 20 - Write the two-resonance structures for the acetate...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - Write two complete balanced equations for each of...Ch. 20 - Yields in organic reactions are sometimes low....Ch. 20 - Alcohols A, B and C all have the composition C4H...Ch. 20 - Write the Lewis structures of both isomers with...Ch. 20 - What is the molecular structure about the nitrogen...Ch. 20 - Write the two resonance structures for the...Ch. 20 - Draw Lewis structures for pyridine and its...Ch. 20 - Write the Lewis structures of all isomers with the...Ch. 20 - Write two complete balanced equations for the...Ch. 20 - Write two complete, balanced equations for each of...Ch. 20 - Identify any carbon atoms that change...Ch. 20 - Identify any carbon atoms that change...Ch. 20 - Identify any carbon atoms that change...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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