Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 20, Problem 26E
Interpretation Introduction

Interpretation:

The reason for the decay of 238U to 206Pb to be useful for dating rocks but useless for dating objects which are 10000 years old needs to be explained. Also, the reason for Carbon-14 dating to be useful for the dating of objects 10000 years old but not for dating rocks needs to be explained.

Concept Introduction:

Carbon-14 dating is a process employed for the determination the age of organic material by using the properties of radiocarbon. The inaccuracy in the carbon dating leads to errors in the process. Radiocarbon dating is a key instrument archeologists used to decide the period of plants and items made with natural material. However, new research shows that usually acknowledged radiocarbon dating guidelines bring up short - raising doubt about verifiable timetables.

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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown.  Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.)  (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)
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Draw a reasonable mechanism for the following reaction:

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