A proposed mechanism for the gas-phase chlorination of methane is Cl 2 + CH 4 → CH 4 Cl + Cl ⋅ CH 4 Cl → CH 3 ⋅ + HCl CH 3 ⋅ + Cl 2 → CH 3 Cl + Cl ⋅ Cl ⋅ + CH 4 → CH 3 ⋅ + HCl Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants, Cl 2 and CH 4 ? How would you determine if this mechanism might be a potentially correct (or, for that matter, a potentially incorrect) one?
A proposed mechanism for the gas-phase chlorination of methane is Cl 2 + CH 4 → CH 4 Cl + Cl ⋅ CH 4 Cl → CH 3 ⋅ + HCl CH 3 ⋅ + Cl 2 → CH 3 Cl + Cl ⋅ Cl ⋅ + CH 4 → CH 3 ⋅ + HCl Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants, Cl 2 and CH 4 ? How would you determine if this mechanism might be a potentially correct (or, for that matter, a potentially incorrect) one?
Solution Summary: The author explains that the expected rate law for the chlorination of methane is to be determined. The rate of reaction depends on several factors such as the concentration of reactant and temperature.
Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants,
Cl
2
and
CH
4
? How would you determine if this mechanism might be a potentially correct (or, for that matter, a potentially incorrect) one?
A block of zinc has an initial temperature of 94.2 degrees celcius and is immererd in 105 g of water at 21.90 degrees celcius. At thermal equilibrium, the final temperature is 25.20 degrees celcius. What is the mass of the zinc block? Cs(Zn) = 0.390 J/gxdegrees celcius Cs(H2O) = 4.18 J/gx degrees celcus
Potential Energy (kJ)
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
AH = -950 kJ
AH = 575 kJ
(i) Cl₂ (g) + Pt (s) 2C1 (g) + Pt (s)
Ea = 1550 kJ
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea = 2240 kJ
Ea = 2350 kJ
AH = -825 kJ
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a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
800
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0
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-400
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Reaction Progress
Can u help me figure out the reaction mechanisms for these, idk where to even start
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