The decomposition of NH 3 : 2 NH 3 → N 2 + 3 H 2 is a zeroth-order reaction that, at elevated temperatures, has a rate constant of 1.04 × 10 − 1 M / s . If the initial concentration of NH 3 is 1.00 M , how long will it take for the concentration to drop to (a) 0.75 M ; (b) 0.50 M ; (c) 0.00 M ?
The decomposition of NH 3 : 2 NH 3 → N 2 + 3 H 2 is a zeroth-order reaction that, at elevated temperatures, has a rate constant of 1.04 × 10 − 1 M / s . If the initial concentration of NH 3 is 1.00 M , how long will it take for the concentration to drop to (a) 0.75 M ; (b) 0.50 M ; (c) 0.00 M ?
Solution Summary: The author explains that the rate of a reaction depends on several factors such as the concentration of reactant and temperature. The integrated rate law for zeroth-order kinetics is represented as, t=left
is a zeroth-order reaction that, at elevated temperatures, has a rate constant of
1.04
×
10
−
1
M
/
s
. If the initial concentration of
NH
3
is
1.00
M
, how long will it take for the concentration to drop to (a)
0.75
M
; (b)
0.50
M
; (c)
0.00
M
?
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
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