(a) Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted. Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

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Answer 1

Question

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

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30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in class, but the partition function that describes the translational and rotational motion of a homonuclear diatomic molecule is given by Itrans (V,T) = = 2πmkBT h² V grot (T) 4π²IKBT h² Where h is Planck's constant and I is molecular moment of inertia. The overall partition function is qmolec Qtrans qrot. Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a volume of 1 m³. Here is some useful data: Moment of inertia: I2 I 7.46 x 10- 45 kg m² 2 O2 I 1.91 x 101 -46 kg m²

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Draw the principal organic product of the following reaction.

Answer 2

Question

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

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Answer 3

Question

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

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Answer 4

Question

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

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Answer 5

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 6

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Answer 7

Chapter 20, Problem 20.47P

Interpretation Introduction

(a)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 12

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 13

Interpretation Introduction

(d)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 14

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 15

Interpretation Introduction

(e)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Grignard reagent is prepared by the reaction of alkyl or aryl bromide with magnesium metal in the presence of ether. The reaction of Grignard reagent with an aldehyde/ketone followed by hydrolysis yields an alcohol.

Answer 16

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 17

Interpretation Introduction

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 18

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 19

Interpretation Introduction

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 20

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 21

Interpretation Introduction

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

Answer 22

Expert Solution & Answer

Answer 23

Expert Solution & Answer

Answer 24

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Answer 25

Ch. 20 - Prob. 20.1P Ch. 20 - Which carbonyl groups in the anticancer drug taxol...Ch. 20 - Prob. 20.3P Ch. 20 - Prob. 20.4P Ch. 20 - Problem 20.5 What aldehyde or ketone is needed to...Ch. 20 - Prob. 20.6P Ch. 20 - Problem 20.7 Draw the products formed when is...Ch. 20 - Prob. 20.8P Ch. 20 - Prob. 20.9P Ch. 20 - Prob. 20.10P

Solution Summary: The author explains that the product formed for the given reaction with organometallic reagents is shown below.

Concept explainers

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

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Chapter 20 Solutions

Solution Summary: The author explains that the product formed for the given reaction with organometallic reagents is shown below.

Concept explainers

(f) Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted. Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

(g) Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted. Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

(h) Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted. Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

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Chapter 20 Solutions

(f)

Interpretation: The product formed for the given reaction with organometallic reagent is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

(g)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.

(h)

Interpretation: The product formed for the given reaction with organometallic reagents is to be predicted.

Concept introduction: Addition of organolithium reagent in the presence of water reduces alkene into alkanes. Organolithium is used as reduction reagent.