(a) Interpretation: The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted. Concept introduction: An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent ( RMgX ) has a polar R-Mg bond; an alkyllithium ( RLi ) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part ( R − ) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

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Answer 1

Question

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Q: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCC

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Answer 2

Question

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

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Answer 3

Question

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

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Answer 4

Question

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

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Answer 5

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Answer 6

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Answer 7

Chapter 20, Problem 20.23P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn, and the major product for the same reaction is to be predicted.

Concept introduction:

An organometallic compound has a polar covalent C-M bond. For example, the Grignard reagent (RMgX) has a polar R-Mg bond; an alkyllithium (RLi) has a polar covalent C-Li bond. Since carbon is bonded with an electropositive element, carbon possesses the partial negative charge and acts as the nucleophile as well as the base. Thus it is used for the new C-C bond formation with electrophilic carbon. The nucleophilic part (R−) of the Grignard reagent shows a nucleophilic addition reaction with electrophilic carbon of the carbonyl compounds.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 20 - Prob. 20.1P Ch. 20 - Prob. 20.2P Ch. 20 - Prob. 20.3P Ch. 20 - Prob. 20.4P Ch. 20 - Prob. 20.5P Ch. 20 - Prob. 20.6P Ch. 20 - Prob. 20.7P Ch. 20 - Prob. 20.8P Ch. 20 - Prob. 20.9P Ch. 20 - Prob. 20.10P

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Chapter 20 Solutions