CHEMISTRY  MOLECULAR NATURE OF MATTER
CHEMISTRY MOLECULAR NATURE OF MATTER
9th Edition
ISBN: 9781266177835
Author: SILBERBERG
Publisher: MCG
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Chapter 20, Problem 20.19P

(a)

Interpretation Introduction

Interpretation:

For the given reaction process, the sign of ΔSo have to be predicted.

    Ag+(aq)+Cl(aq)AgCl(s)

Concept introduction:

Entropy is the measure of randomness in the system.  Standard entropy change in a reaction is the difference in entropy of the products and reactants.  (ΔS°rxn) can be calculated by the following equation.

  ΔS°rxn = S°Products- S°reactants

Where,

  S°reactants is the standard entropy of the reactants

  S°Products is the standard entropy of the products

Standard entropy change in a reaction and entropy change in the system are same.

Entropy(S): It is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state.

If the disorder increases in a system, then ΔS>0

If the disorder decreases in a system, then ΔS<0

If the disorder equal in a system, then ΔS=0

(b)

Interpretation Introduction

Interpretation:

For the given reaction process, the sign of ΔSo have to be predicted.

    KBr(s)KBr(aq)

Concept introduction:

Entropy is the measure of randomness in the system.  Standard entropy change in a reaction is the difference in entropy of the products and reactants.  (ΔS°rxn) can be calculated by the following equation.

  ΔS°rxn = S°Products- S°reactants

Where,

  S°reactants is the standard entropy of the reactants

  S°Products is the standard entropy of the products

Standard entropy change in a reaction and entropy change in the system are same.

Entropy(S): It is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state.

If the disorder increases in a system, then ΔS>0

If the disorder decreases in a system, then ΔS<0

If the disorder equal in a system, then ΔS=0

(c)

Interpretation Introduction

Interpretation:

For the given reaction process, the sign of ΔSo have to be predicted.

    CHEMISTRY  MOLECULAR NATURE OF MATTER, Chapter 20, Problem 20.19P

Concept introduction:

Entropy is the measure of randomness in the system.  Standard entropy change in a reaction is the difference in entropy of the products and reactants.  (ΔS°rxn) can be calculated by the following equation.

  ΔS°rxn = S°Products- S°reactants

Where,

  S°reactants is the standard entropy of the reactants

  S°Products is the standard entropy of the products

Standard entropy change in a reaction and entropy change in the system are same.

Entropy(S): It is used to describe the disorder. It is the amount of arrangements possible in a system at a particular state.

If the disorder increases in a system, then ΔS>0

If the disorder decreases in a system, then ΔS<0

If the disorder equal in a system, then ΔS=0

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Chapter 20 Solutions

CHEMISTRY MOLECULAR NATURE OF MATTER

Ch. 20.3 - Prob. 20.6AFPCh. 20.3 - Prob. 20.6BFPCh. 20.3 - Prob. 20.7AFPCh. 20.3 - Prob. 20.7BFPCh. 20.3 - Prob. 20.8AFPCh. 20.3 - Prob. 20.8BFPCh. 20.4 - Prob. 20.9AFPCh. 20.4 - Prob. 20.9BFPCh. 20.4 - Prob. 20.10AFPCh. 20.4 - Prob. 20.10BFPCh. 20.4 - Prob. 20.11AFPCh. 20.4 - Prob. 20.11BFPCh. 20 - Prob. 20.1PCh. 20 - Distinguish between the terms spontaneous and...Ch. 20 - State the first law of thermodynamics in terms of...Ch. 20 - State qualitatively the relationship between...Ch. 20 - Why is ΔSvap of a substance always larger than...Ch. 20 - Prob. 20.6PCh. 20 - Prob. 20.7PCh. 20 - Which of these processes are spontaneous? (a)...Ch. 20 - Prob. 20.9PCh. 20 - Which of these processes are spontaneous? (a)...Ch. 20 - Prob. 20.11PCh. 20 - Prob. 20.12PCh. 20 - Prob. 20.13PCh. 20 - Prob. 20.14PCh. 20 - Prob. 20.15PCh. 20 - Prob. 20.16PCh. 20 - Prob. 20.17PCh. 20 - Prob. 20.18PCh. 20 - Prob. 20.19PCh. 20 - Prob. 20.20PCh. 20 - Prob. 20.21PCh. 20 - Prob. 20.22PCh. 20 - Prob. 20.23PCh. 20 - Prob. 20.24PCh. 20 - Predict which substance has greater molar entropy....Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - In the reaction depicted in the molecular scenes,...Ch. 20 - Describe the equilibrium condition in terms of the...Ch. 20 - Prob. 20.32PCh. 20 - For each reaction, predict the sign and find the...Ch. 20 - For each reaction, predict the sign and find the...Ch. 20 - Find for the combustion of ethane (C2H6) to...Ch. 20 - Find for the combustion of methane to carbon...Ch. 20 - Find for the reaction of nitrogen monoxide with...Ch. 20 - Find for the combustion of ammonia to nitrogen...Ch. 20 - Find for the formation of Cu2O(s) from its...Ch. 20 - Find for the formation of HI(g) from its...Ch. 20 - Find for the formation of CH3OH(l) from its...Ch. 20 - Find for the formation of N2O(g) from its...Ch. 20 - Sulfur dioxide is released in the combustion of...Ch. 20 - Oxyacetylene welding is used to repair metal...Ch. 20 - What is the advantage of calculating free energy...Ch. 20 - Given that ΔGsys = −TΔSuniv, explain how the sign...Ch. 20 - Is an endothermic reaction more likely to be...Ch. 20 - Explain your answers to each of the following for...Ch. 20 - With its components in their standard states, a...Ch. 20 - How can ΔS° for a reaction be relatively...Ch. 20 - Calculate ΔG° for each reaction using ...Ch. 20 - Calculate ΔG° for each reaction using ...Ch. 20 - Prob. 20.53PCh. 20 - Prob. 20.54PCh. 20 - Consider the oxidation of carbon...Ch. 20 - Consider the combustion of butane gas: Predict...Ch. 20 - For the gaseous reaction of xenon and fluorine to...Ch. 20 - For the gaseous reaction of carbon monoxide and...Ch. 20 - One reaction used to produce small quantities of...Ch. 20 - A reaction that occurs in the internal combustion...Ch. 20 - As a fuel, H2(g) produces only nonpolluting H2O(g)...Ch. 20 - The U.S. government requires automobile fuels to...Ch. 20 - If K << 1 for a reaction, what do you know about...Ch. 20 - How is the free energy change of a process related...Ch. 20 - The scenes and the graph relate to the reaction of...Ch. 20 - What is the difference between ΔG° and ΔG? Under...Ch. 20 - Calculate K at 298 K for each reaction: MgCO3(s) ⇌...Ch. 20 - Calculate ΔG° at 298 K for each reaction: 2H2S(g)...Ch. 20 - Calculate K at 298 K for each reaction: HCN(aq) +...Ch. 20 - Calculate ΔG° at 298 K for each reaction: 2NO(g) +...Ch. 20 - Use ΔH° and ΔS° values for the following process...Ch. 20 - Use ΔH° and ΔS° values to find the temperature at...Ch. 20 - Prob. 20.73PCh. 20 - Use Appendix B to determine the Ksp of CaF2. Ch. 20 - For the reaction I2(g) + Cl2(g) ⇌ 2ICl(g),...Ch. 20 - For the reaction CaCO3(s) ⇌ CaO(s) + CO2(g),...Ch. 20 - The Ksp of PbCl2 is 1.7×10−5 at 25°C. What is ΔG°?...Ch. 20 - Prob. 20.78PCh. 20 - The equilibrium constant for the...Ch. 20 - The formation constant for the reaction Ni2+(aq) +...Ch. 20 - Prob. 20.81PCh. 20 - Prob. 20.82PCh. 20 - High levels of ozone (O3) cause rubber to...Ch. 20 - A BaSO4 slurry is ingested before the...Ch. 20 - According to advertisements, “a diamond is...Ch. 20 - Prob. 20.86PCh. 20 - Prob. 20.87PCh. 20 - Prob. 20.88PCh. 20 - Is each statement true or false? If false, correct...Ch. 20 - Prob. 20.90PCh. 20 - Prob. 20.91PCh. 20 - Prob. 20.92PCh. 20 - Prob. 20.93PCh. 20 - Write a balanced equation for the gaseous...Ch. 20 - Prob. 20.95PCh. 20 - Hydrogenation is the addition of H2 to double (or...Ch. 20 - Prob. 20.97PCh. 20 - Prob. 20.98PCh. 20 - Prob. 20.99PCh. 20 - Prob. 20.100PCh. 20 - From the following reaction and data, find (a) S°...Ch. 20 - Prob. 20.102PCh. 20 - Prob. 20.103PCh. 20 - Prob. 20.104PCh. 20 - Prob. 20.105PCh. 20 - Prob. 20.106PCh. 20 - Prob. 20.107PCh. 20 - Consider the formation of ammonia: N2(g) + 3H2(g)...Ch. 20 - Kyanite, sillimanite, and andalusite all have the...Ch. 20 - Prob. 20.110PCh. 20 - Prob. 20.111P
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