Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 2, Problem IISP

(a)

Interpretation Introduction

Interpretation:

The correct formula of ammonium dichromate, ammonium nitrate and trinitrotoluene has to be written.

(a)

Expert Solution
Check Mark

Explanation of Solution

(i)Ammonium dichromate contains the ammonium cation, NH4+ and the dichromate anion Cr2O72-.  The compound must have two +1 cations to balance the charge of the 2- anion, so its formula is (NH4)2Cr2O7.

(ii)Ammonium nitrate contains the ammonium cation, NH4+ and the nitrate anion, NO3-.  The compound must have one +1 cation to balance the charge of the 1- anion, so its formula is NH4NO3.

(iii)Trinitrotoluene contains seven carbon atoms, five hydrogen atoms, three nitrogen atoms and six oxygen atoms, so its formula is C7H5N3O6.

(b)

Interpretation Introduction

Interpretation:

Among the three compounds given, the compound which has the highest mass percent nitrogen has to be determined.

(b)

Expert Solution
Check Mark

Explanation of Solution

(i)Ammonium dichromate:

Formula is. (NH4)2Cr2O7

One mole of (NH4)2Cr2O7 contains two moles of nitrogen.

Molar mass of (NH4)2Cr2O7 is:

=(2×14.0067g/molN)+(8×1.0079g/molH)+(2×51.9961g/molCr)+(7×15.9994g/molO)=252.0646g/mol.

Mass of N in one mole of (NH4)2Cr2O7

=2×14.0067g/molN=28.0134g/molN.

%N=massNpermolmasscompoundpermol×100%=28.0134gN252.0646compound×100%=11.1136%

(ii)Ammonium nitrate:

Formula is NH4NO3.

One mole of NH4NO3 contains two moles of nitrogen.

Molar mass of NH4NO3 is:

=(2×14.0067g/molN)+(4×1.0079g/molH))+(3×15.9994g/molO)=80.0432g/mol.

Mass of N in one mole of NH4NO3 =2×14.0067g/molN=28.0134g/molN.

%N=massNpermolmasscompoundpermol×100%=28.0134gN80.0432gcompound×100%=34.9979%

(iii)Trinitrotoluene:

Formula is C7H5N3O6.

One mole of C7H5N3O6 contains three moles of nitrogen.

Molar mass of C7H5N3O6 is:

  =(7×12.0107g/molC)+(3×14.0067g/molN)+(5×1.0079g/molH))+(6×15.9994g/molO)=227.1309g/mol.

Mass of N in one mole of C7H5N3O6 =3×14.0067g/molN=42.0201g/molN.

%N=massNpermolmasscompoundpermol×100%=42.0201gN227.1309gcompound×100%=18.5004%N

(c)

Interpretation Introduction

Interpretation:

Among the three compounds, the compound which has the lowest melting point has to be explained.

(c)

Expert Solution
Check Mark

Explanation of Solution

Molecular compounds have lower melting points than ionic compounds.  (NH4)2Cr2O7 and NH4NO3 are ionic compounds and C7H5N3O6 is a molecular compound.  So trinitrotoluene will have the lowest melting point.

(d)

Interpretation Introduction

Interpretation:

Among the three compounds, the compound which conduct electricity at room temperature has to be explained.

(d)

Expert Solution
Check Mark

Explanation of Solution

(NH4)2Cr2O7, NH4NO3 and C7H5N3O6 are the given compounds and all the three compounds are solid at room temperature.  If the temperature were high enough to melt the ionic compounds (NH4)2Cr2O7, NH4NO3 the molten ions would conduct electricity.  The molecular compound C7H5N3O6 will not conduct electricity at any temperature.

(e)

Interpretation Introduction

Interpretation:

Among the three compounds, the compound which conducts electricity if they melted has to be given.

(e)

Expert Solution
Check Mark

Explanation of Solution

If the temperature of the ionic compounds increased, then the ions will melt and in that molten state would electricity.  So (NH4)2Cr2O7, NH4NO3 can conduct electricity in molten state.

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Chapter 2 Solutions

Chemistry: The Molecular Science

Ch. 2.4 - Prob. 2.6PSPCh. 2.4 - Prob. 2.6CECh. 2.4 - Prob. 2.7PSPCh. 2.4 - Prob. 2.8PSPCh. 2.5 - Prob. 2.9PSPCh. 2.5 - Prob. 2.10PSPCh. 2.6 - Prob. 2.7CECh. 2.7 - Prob. 2.8CECh. 2.7 - Prob. 2.11PSPCh. 2.7 - Prob. 2.9ECh. 2.8 - Prob. 2.12PSPCh. 2.8 - Prob. 2.10ECh. 2.9 - Prob. 2.11ECh. 2.9 - Prob. 2.12ECh. 2.9 - Prob. 2.13CECh. 2.9 - According to Table 2.10, five constitutional...Ch. 2.11 - Calculate (a) the amount of Ti atoms in 4.00 g...Ch. 2.11 - Prob. 2.15CECh. 2.11 - Prob. 2.16ECh. 2.11 - Prob. 2.17CECh. 2.11 - Prob. 2.18ECh. 2.11 - Prob. 2.19ECh. 2.11 - Prob. 2.14PSPCh. 2.11 - Prob. 2.15PSPCh. 2.11 - Prob. 2.16PSPCh. 2.11 - Prob. 2.20CECh. 2.12 - Prob. 2.17PSPCh. 2.12 - Prob. 2.18PSPCh. 2.12 - Prob. 2.21ECh. 2.12 - Hydrazine is composed of 87.42% nitrogen and...Ch. 2.12 - Prob. 2.20PSPCh. 2.12 - Prob. 2.22ECh. 2 - An isotope of an element contains 63 protons and...Ch. 2 - Prob. IISPCh. 2 - Prob. IIISPCh. 2 - Dioxathion, a pesticide, contains carbon,...Ch. 2 - Prob. 1QRTCh. 2 - Prob. 2QRTCh. 2 - Prob. 3QRTCh. 2 - Prob. 4QRTCh. 2 - Prob. 5QRTCh. 2 - Prob. 6QRTCh. 2 - Prob. 7QRTCh. 2 - Prob. 8QRTCh. 2 - Prob. 9QRTCh. 2 - Prob. 10QRTCh. 2 - Match these by placing the correct notation in the...Ch. 2 - Prob. 12QRTCh. 2 - Prob. 13QRTCh. 2 - Prob. 14QRTCh. 2 - Prob. 15QRTCh. 2 - Prob. 16QRTCh. 2 - Prob. 17QRTCh. 2 - Prob. 18QRTCh. 2 - Prob. 19QRTCh. 2 - Prob. 20QRTCh. 2 - Prob. 21QRTCh. 2 - Prob. 22QRTCh. 2 - Prob. 23QRTCh. 2 - Prob. 24QRTCh. 2 - Prob. 25QRTCh. 2 - Prob. 26QRTCh. 2 - Prob. 27QRTCh. 2 - Prob. 28QRTCh. 2 - Argon has three naturally occurring isotopes:...Ch. 2 - Prob. 30QRTCh. 2 - Prob. 31QRTCh. 2 - Prob. 32QRTCh. 2 - Prob. 33QRTCh. 2 - Prob. 34QRTCh. 2 - Prob. 35QRTCh. 2 - Prob. 36QRTCh. 2 - Prob. 37QRTCh. 2 - Prob. 38QRTCh. 2 - Prob. 39QRTCh. 2 - Prob. 40QRTCh. 2 - Prob. 41QRTCh. 2 - Prob. 42QRTCh. 2 - Prob. 43QRTCh. 2 - Prob. 44QRTCh. 2 - Prob. 45QRTCh. 2 - Prob. 46QRTCh. 2 - Prob. 47QRTCh. 2 - Prob. 48QRTCh. 2 - Prob. 49QRTCh. 2 - Prob. 50QRTCh. 2 - Prob. 51QRTCh. 2 - Prob. 52QRTCh. 2 - Prob. 53QRTCh. 2 - Prob. 54QRTCh. 2 - Prob. 55QRTCh. 2 - Prob. 56QRTCh. 2 - Prob. 57QRTCh. 2 - Prob. 58QRTCh. 2 - Prob. 59QRTCh. 2 - Prob. 60QRTCh. 2 - Prob. 61QRTCh. 2 - Prob. 62QRTCh. 2 - Prob. 63QRTCh. 2 - Prob. 64QRTCh. 2 - Prob. 65QRTCh. 2 - Prob. 66QRTCh. 2 - Prob. 67QRTCh. 2 - Prob. 68QRTCh. 2 - Prob. 69QRTCh. 2 - Prob. 70QRTCh. 2 - Prob. 71QRTCh. 2 - Prob. 72QRTCh. 2 - Prob. 73QRTCh. 2 - Prob. 74QRTCh. 2 - If you have a ring that contains 1.94 g gold,...Ch. 2 - You have a pure sample of the antiseptic...Ch. 2 - You have a pure sample of apholate, C12H24N9P3, a...Ch. 2 - Prob. 78QRTCh. 2 - Prob. 79QRTCh. 2 - Prob. 80QRTCh. 2 - Prob. 81QRTCh. 2 - Prob. 82QRTCh. 2 - Prob. 83QRTCh. 2 - Prob. 84QRTCh. 2 - Prob. 85QRTCh. 2 - Prob. 86QRTCh. 2 - Prob. 87QRTCh. 2 - Prob. 88QRTCh. 2 - Prob. 89QRTCh. 2 - Prob. 90QRTCh. 2 - Quinine (molar mass = 324.41 g/mol) is used as a...Ch. 2 - Prob. 92QRTCh. 2 - The mineral uraninite is a uranium oxide that is...Ch. 2 - Carbonic anhydrase, an important enzyme in...Ch. 2 - Nitrogen fixation in the root nodules of peas and...Ch. 2 - Disilane, Si2Hx, contains 90.28% silicon by mass....Ch. 2 - Chalky, white crystals in mineral collections are...Ch. 2 - A well-known reagent in analytical chemistry,...Ch. 2 - Prob. 99QRTCh. 2 - Prob. 100QRTCh. 2 - The density of a solution of sulfuric acid is...Ch. 2 - Prob. 102QRTCh. 2 - Prob. 103QRTCh. 2 - Prob. 104QRTCh. 2 - Prob. 105QRTCh. 2 - Prob. 106QRTCh. 2 - Prob. 107QRTCh. 2 - The Statue of Liberty in New York harbor is made...Ch. 2 - Prob. 109QRTCh. 2 - Prob. 110QRTCh. 2 - Prob. 111QRTCh. 2 - Prob. 112QRTCh. 2 - Prob. 113QRTCh. 2 - Prob. 114QRTCh. 2 - Prob. 115QRTCh. 2 - Prob. 116QRTCh. 2 - Prob. 117QRTCh. 2 - Prob. 118QRTCh. 2 - Prob. 119QRTCh. 2 - Prob. 120QRTCh. 2 - Prob. 121QRTCh. 2 - Prob. 122QRTCh. 2 - Prob. 123QRTCh. 2 - Prob. 124QRTCh. 2 - Prob. 125QRTCh. 2 - Prob. 126QRTCh. 2 - Prob. 127QRTCh. 2 - Prob. 128QRTCh. 2 - Prob. 129QRTCh. 2 - The element bromine is Br2, so the mass of a Br2...Ch. 2 - Uranium is used as a fuel, primarily in the form...Ch. 2 - Prob. 132QRTCh. 2 - Hemoglobin is an iron-containing protein (molar...Ch. 2 - There are three naturally occurring isotopes of...Ch. 2 - Prob. 135QRTCh. 2 - Prob. 136QRTCh. 2 - Prob. 137QRTCh. 2 - An adult human body contains 6.0 L blood, which...Ch. 2 - Prob. 139QRTCh. 2 - Prob. 140QRTCh. 2 - Prob. 141QRTCh. 2 - The present average concentration (mass percent)...Ch. 2 - Prob. 144QRTCh. 2 - A 4.22-g mixture of calcium chloride and sodium...Ch. 2 - A certain metal, M, forms two oxides, M2O and MO....Ch. 2 - If you heat Al with an element from Group 6A, an...Ch. 2 - Prob. 2.ACPCh. 2 - The age of the universe is unknown, but some...Ch. 2 - Prob. 2.CCPCh. 2 - Prob. 2.DCPCh. 2 - Prob. 2.ECP
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