Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 2, Problem 74QRT
Interpretation Introduction
Interpretation:
If
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Please identify the one structure below that is consistent with the 'H NMR and IR spectra
shown and draw its complete structure in the box below with the protons alphabetically labeled as
shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by
the arrows.
D
4000
OH
LOH
H₂C
CH3
OH
H₂C
OCH3
CH3
OH
3000
2000
1500
HAVENUMBERI-11
1000
LOCH3
Draw your structure below and label its equivalent protons according to the peak labeling that is used
in the NMR spectrum in order to assign the peaks.
Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet
8
3Hb s
m
1Hd s
3Hf
m 2Hcd
2Had
1He
鄙视
m
7
7
6
5
4
3
22
500
T
1
0
Chapter 2 Solutions
Chemistry: The Molecular Science
Ch. 2.1 - When you comb your hair on a dry day, your hair...Ch. 2.2 - Prob. 2.1PSPCh. 2.2 - Prob. 2.2PSPCh. 2.2 - Prob. 2.2CECh. 2.2 - Prob. 2.3PSPCh. 2.3 - Prob. 2.4PSPCh. 2.3 - A student in your chemistry class tells you that...Ch. 2.3 - Prob. 2.5PSPCh. 2.3 - Prob. 2.4CECh. 2.3 - Prob. 2.5CE
Ch. 2.4 - Prob. 2.6PSPCh. 2.4 - Prob. 2.6CECh. 2.4 - Prob. 2.7PSPCh. 2.4 - Prob. 2.8PSPCh. 2.5 - Prob. 2.9PSPCh. 2.5 - Prob. 2.10PSPCh. 2.6 - Prob. 2.7CECh. 2.7 - Prob. 2.8CECh. 2.7 - Prob. 2.11PSPCh. 2.7 - Prob. 2.9ECh. 2.8 - Prob. 2.12PSPCh. 2.8 - Prob. 2.10ECh. 2.9 - Prob. 2.11ECh. 2.9 - Prob. 2.12ECh. 2.9 - Prob. 2.13CECh. 2.9 - According to Table 2.10, five constitutional...Ch. 2.11 - Calculate (a) the amount of Ti atoms in 4.00 g...Ch. 2.11 - Prob. 2.15CECh. 2.11 - Prob. 2.16ECh. 2.11 - Prob. 2.17CECh. 2.11 - Prob. 2.18ECh. 2.11 - Prob. 2.19ECh. 2.11 - Prob. 2.14PSPCh. 2.11 - Prob. 2.15PSPCh. 2.11 - Prob. 2.16PSPCh. 2.11 - Prob. 2.20CECh. 2.12 - Prob. 2.17PSPCh. 2.12 - Prob. 2.18PSPCh. 2.12 - Prob. 2.21ECh. 2.12 - Hydrazine is composed of 87.42% nitrogen and...Ch. 2.12 - Prob. 2.20PSPCh. 2.12 - Prob. 2.22ECh. 2 - An isotope of an element contains 63 protons and...Ch. 2 - Prob. IISPCh. 2 - Prob. IIISPCh. 2 - Dioxathion, a pesticide, contains carbon,...Ch. 2 - Prob. 1QRTCh. 2 - Prob. 2QRTCh. 2 - Prob. 3QRTCh. 2 - Prob. 4QRTCh. 2 - Prob. 5QRTCh. 2 - Prob. 6QRTCh. 2 - Prob. 7QRTCh. 2 - Prob. 8QRTCh. 2 - Prob. 9QRTCh. 2 - Prob. 10QRTCh. 2 - Match these by placing the correct notation in the...Ch. 2 - Prob. 12QRTCh. 2 - Prob. 13QRTCh. 2 - Prob. 14QRTCh. 2 - Prob. 15QRTCh. 2 - Prob. 16QRTCh. 2 - Prob. 17QRTCh. 2 - Prob. 18QRTCh. 2 - Prob. 19QRTCh. 2 - Prob. 20QRTCh. 2 - Prob. 21QRTCh. 2 - Prob. 22QRTCh. 2 - Prob. 23QRTCh. 2 - Prob. 24QRTCh. 2 - Prob. 25QRTCh. 2 - Prob. 26QRTCh. 2 - Prob. 27QRTCh. 2 - Prob. 28QRTCh. 2 - Argon has three naturally occurring isotopes:...Ch. 2 - Prob. 30QRTCh. 2 - Prob. 31QRTCh. 2 - Prob. 32QRTCh. 2 - Prob. 33QRTCh. 2 - Prob. 34QRTCh. 2 - Prob. 35QRTCh. 2 - Prob. 36QRTCh. 2 - Prob. 37QRTCh. 2 - Prob. 38QRTCh. 2 - Prob. 39QRTCh. 2 - Prob. 40QRTCh. 2 - Prob. 41QRTCh. 2 - Prob. 42QRTCh. 2 - Prob. 43QRTCh. 2 - Prob. 44QRTCh. 2 - Prob. 45QRTCh. 2 - Prob. 46QRTCh. 2 - Prob. 47QRTCh. 2 - Prob. 48QRTCh. 2 - Prob. 49QRTCh. 2 - Prob. 50QRTCh. 2 - Prob. 51QRTCh. 2 - Prob. 52QRTCh. 2 - Prob. 53QRTCh. 2 - Prob. 54QRTCh. 2 - Prob. 55QRTCh. 2 - Prob. 56QRTCh. 2 - Prob. 57QRTCh. 2 - Prob. 58QRTCh. 2 - Prob. 59QRTCh. 2 - Prob. 60QRTCh. 2 - Prob. 61QRTCh. 2 - Prob. 62QRTCh. 2 - Prob. 63QRTCh. 2 - Prob. 64QRTCh. 2 - Prob. 65QRTCh. 2 - Prob. 66QRTCh. 2 - Prob. 67QRTCh. 2 - Prob. 68QRTCh. 2 - Prob. 69QRTCh. 2 - Prob. 70QRTCh. 2 - Prob. 71QRTCh. 2 - Prob. 72QRTCh. 2 - Prob. 73QRTCh. 2 - Prob. 74QRTCh. 2 - If you have a ring that contains 1.94 g gold,...Ch. 2 - You have a pure sample of the antiseptic...Ch. 2 - You have a pure sample of apholate, C12H24N9P3, a...Ch. 2 - Prob. 78QRTCh. 2 - Prob. 79QRTCh. 2 - Prob. 80QRTCh. 2 - Prob. 81QRTCh. 2 - Prob. 82QRTCh. 2 - Prob. 83QRTCh. 2 - Prob. 84QRTCh. 2 - Prob. 85QRTCh. 2 - Prob. 86QRTCh. 2 - Prob. 87QRTCh. 2 - Prob. 88QRTCh. 2 - Prob. 89QRTCh. 2 - Prob. 90QRTCh. 2 - Quinine (molar mass = 324.41 g/mol) is used as a...Ch. 2 - Prob. 92QRTCh. 2 - The mineral uraninite is a uranium oxide that is...Ch. 2 - Carbonic anhydrase, an important enzyme in...Ch. 2 - Nitrogen fixation in the root nodules of peas and...Ch. 2 - Disilane, Si2Hx, contains 90.28% silicon by mass....Ch. 2 - Chalky, white crystals in mineral collections are...Ch. 2 - A well-known reagent in analytical chemistry,...Ch. 2 - Prob. 99QRTCh. 2 - Prob. 100QRTCh. 2 - The density of a solution of sulfuric acid is...Ch. 2 - Prob. 102QRTCh. 2 - Prob. 103QRTCh. 2 - Prob. 104QRTCh. 2 - Prob. 105QRTCh. 2 - Prob. 106QRTCh. 2 - Prob. 107QRTCh. 2 - The Statue of Liberty in New York harbor is made...Ch. 2 - Prob. 109QRTCh. 2 - Prob. 110QRTCh. 2 - Prob. 111QRTCh. 2 - Prob. 112QRTCh. 2 - Prob. 113QRTCh. 2 - Prob. 114QRTCh. 2 - Prob. 115QRTCh. 2 - Prob. 116QRTCh. 2 - Prob. 117QRTCh. 2 - Prob. 118QRTCh. 2 - Prob. 119QRTCh. 2 - Prob. 120QRTCh. 2 - Prob. 121QRTCh. 2 - Prob. 122QRTCh. 2 - Prob. 123QRTCh. 2 - Prob. 124QRTCh. 2 - Prob. 125QRTCh. 2 - Prob. 126QRTCh. 2 - Prob. 127QRTCh. 2 - Prob. 128QRTCh. 2 - Prob. 129QRTCh. 2 - The element bromine is Br2, so the mass of a Br2...Ch. 2 - Uranium is used as a fuel, primarily in the form...Ch. 2 - Prob. 132QRTCh. 2 - Hemoglobin is an iron-containing protein (molar...Ch. 2 - There are three naturally occurring isotopes of...Ch. 2 - Prob. 135QRTCh. 2 - Prob. 136QRTCh. 2 - Prob. 137QRTCh. 2 - An adult human body contains 6.0 L blood, which...Ch. 2 - Prob. 139QRTCh. 2 - Prob. 140QRTCh. 2 - Prob. 141QRTCh. 2 - The present average concentration (mass percent)...Ch. 2 - Prob. 144QRTCh. 2 - A 4.22-g mixture of calcium chloride and sodium...Ch. 2 - A certain metal, M, forms two oxides, M2O and MO....Ch. 2 - If you heat Al with an element from Group 6A, an...Ch. 2 - Prob. 2.ACPCh. 2 - The age of the universe is unknown, but some...Ch. 2 - Prob. 2.CCPCh. 2 - Prob. 2.DCPCh. 2 - Prob. 2.ECP
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- Relative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forwardCalculate the pH of 0.0025 M phenol.arrow_forwardIn the following reaction, the OH- acts as which of these? NO2-(aq) + H2O(l) ⇌ OH-(aq) + HNO2(aq)arrow_forward
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