
Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 2, Problem 8QP
For the two compounds pictured, evaluate the following ratio:
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 2 Solutions
Chemistry
Ch. 2.1 - Practice Problem ATTEMPT
In each case, calculate...Ch. 2.1 - Practice Problem BUILD
(a) Two of the simplest...Ch. 2.1 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 2.1 - For the two compounds pictured, evaluate the...Ch. 2.1 - Prob. 2CPCh. 2.2 - Practice ProblemATTEMPT How many protons,...Ch. 2.2 - Practice ProblemBUILD Give the correct symbols to...Ch. 2.2 - Prob. 1PPCCh. 2.3 - 2.3.1 How many neutrons are there in an atom of
Ch. 2.3 - Prob. 2CP
Ch. 2.3 - Practice ProblemATTEMPT The atomic masses of the...Ch. 2.3 - Practice ProblemBUILD The average atomic mass of...Ch. 2.3 - Practice Problem CONCEPTUALIZE
The following...Ch. 2.4 - Which of the following series of elemental symbols...Ch. 2.4 - 2.4.2 Which of the following elements would you...Ch. 2.4 - Practice ProblemATTEMPT Chloroform was used as an...Ch. 2.4 - Practice ProblemBUILD Write the molecular formula...Ch. 2.4 - Prob. 1PPCCh. 2.5 - Boron has two naturally occurring isotopes, which...Ch. 2.5 - 2.5.2 The two naturally occurring isotopes of...Ch. 2.5 - Practice Problem ATTEMPT
Name the following...Ch. 2.5 - Practice ProblemBUILD Name the following binary...Ch. 2.5 - Practice Problem CONCEPTUALIZE
Name the binary...Ch. 2.6 - Practice ProblemATTEMPT Give the molecular formula...Ch. 2.6 - Practice ProblemBUILD Give the molecular formula...Ch. 2.6 - Prob. 1PPCCh. 2.6 - Prob. 1CPCh. 2.6 - 2.7.2 What is the name of the compound...Ch. 2.6 - What is the correct formula for the compound...Ch. 2.6 - 2.7.4 What is the empirical formula of the...Ch. 2.7 - Prob. 1CPCh. 2.7 - Prob. 2CPCh. 2.7 - Prob. 3CPCh. 2.7 - 2.6.4 What is the formula of nickel(II) nitrate...Ch. 2.7 - Prob. 5CPCh. 2.7 - Prob. 6CPCh. 2.7 - Practice Problem ATTEMPT
Write empirical formulas...Ch. 2.7 - Practice ProblemBUILD For which of the following...Ch. 2.7 - Practice ProblemCONCEPTUALIZE Which of the...Ch. 2.8 - Practice Problem ATTEMPT
Name the following ionic...Ch. 2.8 - Practice Problem BUILD
Name the following ionic...Ch. 2.8 - Practice ProblemCONCEPTUALIZE The diagram...Ch. 2.9 - Practice Problem ATTEMPT
Deduce the formulas of...Ch. 2.9 - Practice ProblemBUILD Deduce the formulas of the...Ch. 2.9 - Practice Problem CONCEPTUALIZE
The diagram...Ch. 2.10 - Name the following species:...Ch. 2.10 - Name the following species:...Ch. 2.10 - Prob. 1PPCCh. 2.11 - Practice ProblemATTEMPT Determine the formula of...Ch. 2.11 - Practice ProblemBUILD Determine the formula of...Ch. 2.11 - Practice ProblemCONCEPTUALIZE Referring to the...Ch. 2 - Prob. 1KSPCh. 2 - Prob. 2KSPCh. 2 - Prob. 3KSPCh. 2 - What is the correct formula for phosphorus...Ch. 2 - What are the hypotheses on which Dalton's atomic...Ch. 2 - State the laws of definite proportions and...Ch. 2 - Prob. 3QPCh. 2 - Prob. 4QPCh. 2 - 2.5 Sulfur reacts with fluorine to produce three...Ch. 2 - 2.6 Both and contain only iron and oxygen. The...Ch. 2 - For the two compounds pictured, evaluate the...Ch. 2 - 2.8 For the two compounds pictured, evaluate the...Ch. 2 - Prob. 9QPCh. 2 - Prob. 10QPCh. 2 - Prob. 11QPCh. 2 - Describe the contributions of the following...Ch. 2 - 2.13 Describe the experimental basis for believing...Ch. 2 - The diameter of a neutral helium atom is about 1 ×...Ch. 2 - Prob. 15QPCh. 2 - Prob. 16QPCh. 2 - Prob. 17QPCh. 2 - Prob. 18QPCh. 2 - Prob. 19QPCh. 2 - 2.20 What is the mass number of an iron atom that...Ch. 2 - Prob. 21QPCh. 2 - 2.22 For each of the following species, determine...Ch. 2 - 2.23 Indicate the number of protons, neutrons, and...Ch. 2 - Prob. 24QPCh. 2 - Prob. 25QPCh. 2 - Prob. 26QPCh. 2 - Prob. 27QPCh. 2 - Prob. 28QPCh. 2 - What is the periodic table, and what is its...Ch. 2 - 2.30 State two differences between a metal and a...Ch. 2 - Prob. 31QPCh. 2 - Give two examples of each of the following: (a)...Ch. 2 - Prob. 33QPCh. 2 - Prob. 34QPCh. 2 - Prob. 35QPCh. 2 - Prob. 36QPCh. 2 - Prob. 37QPCh. 2 - Prob. 38QPCh. 2 - Prob. 39QPCh. 2 - Prob. 40QPCh. 2 - Prob. 41QPCh. 2 - Prob. 42QPCh. 2 - Prob. 43QPCh. 2 - The atomic masses of 1735Cl(75.53percent) and...Ch. 2 - The atomic masses of 204 Pb ( 1 .4 percent ) . 206...Ch. 2 - Prob. 46QPCh. 2 - Prob. 47QPCh. 2 - 2.48 What is the mass in grams of 13.2 amu?
Ch. 2 - Prob. 49QPCh. 2 - Prob. 71QPCh. 2 - Prob. 72QPCh. 2 - Prob. 73QPCh. 2 - Prob. 74QPCh. 2 - Prob. 75QPCh. 2 - Prob. 76QPCh. 2 - Prob. 77QPCh. 2 - Prob. 78QPCh. 2 - Prob. 79QPCh. 2 - Prob. 80QPCh. 2 - 2.61 Name the following compounds:
Ch. 2 - Prob. 82QPCh. 2 - Prob. 83QPCh. 2 - Prob. 84QPCh. 2 - Prob. 85QPCh. 2 - Prob. 86QPCh. 2 - Prob. 50QPCh. 2 - Prob. 51QPCh. 2 - Prob. 52QPCh. 2 - Prob. 53QPCh. 2 - Prob. 54QPCh. 2 - Prob. 55QPCh. 2 - Prob. 56QPCh. 2 - Prob. 57QPCh. 2 - Prob. 58QPCh. 2 - Prob. 59QPCh. 2 - Prob. 60QPCh. 2 - Prob. 61QPCh. 2 - Prob. 62QPCh. 2 - Prob. 63QPCh. 2 - Prob. 64QPCh. 2 - Prob. 65QPCh. 2 - Prob. 66QPCh. 2 - Prob. 67QPCh. 2 - Prob. 68QPCh. 2 - Prob. 69QPCh. 2 - Prob. 70QPCh. 2 - Prob. 87APCh. 2 - Prob. 88APCh. 2 - Prob. 89APCh. 2 - Prob. 90APCh. 2 - Prob. 91APCh. 2 - Prob. 92APCh. 2 - 2.93 What is wrong with or ambiguous about the...Ch. 2 - Prob. 94APCh. 2 - Prob. 95APCh. 2 - Prob. 96APCh. 2 - Prob. 97APCh. 2 - Prob. 98APCh. 2 - Prob. 99APCh. 2 - Prob. 100APCh. 2 - Prob. 101APCh. 2 - Prob. 102APCh. 2 - Prob. 103APCh. 2 - Determine the molecular and empirical formulas of...Ch. 2 - Prob. 105APCh. 2 - Prob. 106APCh. 2 - The Group 1B metals . Cu, Ag, and Au, are called...Ch. 2 - Prob. 108APCh. 2 - Prob. 109APCh. 2 - Prob. 110APCh. 2 - Two elements form a compound that can be...Ch. 2 - Which of the diagrams can be used to illustrate...Ch. 2 - Prob. 113APCh. 2 - Prob. 114APCh. 2 - Prob. 115APCh. 2 - 2.116 Show the locations of (a) alkali metals, (b)...Ch. 2 - Prob. 117APCh. 2 - Prob. 118APCh. 2 - Prob. 119APCh. 2 - 2.120 (a) Describe Rutherford’s experiment and how...Ch. 2 - Prob. 121APCh. 2 - Prob. 122APCh. 2 - Prob. 123APCh. 2 - A cube made of platinum (Pt) has an edge length of...Ch. 2 - Prob. 125APCh. 2 - Prob. 126APCh. 2 - Prob. 1SEPPCh. 2 - Prob. 2SEPPCh. 2 - Prob. 3SEPPCh. 2 - Prob. 4SEPP
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