Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 2, Problem 6E
How are electrons and protons similar? How are they different?
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Can you please explain why structure 3 is the correct answer? Please give a detailed explanation.
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
Chapter 2 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 2 - In the following drawing, the green spheres...Ch. 2 - Which postulate of Dalton’s theory is consistent...Ch. 2 - Identify the postulate of Dalton’s theory that is...Ch. 2 - Samples of compound X, Y, and Z are analyzed, with...Ch. 2 - The existence of isotopes violates one of the...Ch. 2 - How are electrons and protons similar? How are...Ch. 2 - How are protons and neutrons similar? How are they...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - In what way are isotopes of a given element always...
Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - The following are properties of isotopes of two...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Click on the site...Ch. 2 - Click on the site...Ch. 2 - An element has the following natural abundances...Ch. 2 - Average atomic masses listed by JUPAC are based on...Ch. 2 - Variations in average atomic mass may be observed...Ch. 2 - The average atomic masses of some elements may...Ch. 2 - The 18O:16O abundance ratio in some meteorites is...Ch. 2 - Explain why the symbol for an atom of the element...Ch. 2 - Explain why the symbol for the element sulfur and...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Write the empirical formulas for the following...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Using the periodic table, classify each of the...Ch. 2 - Using the periodic table, classify each of the...Ch. 2 - Using the periodic table, Identify the lightest...Ch. 2 - Using the periodic table, Identify the heaviest...Ch. 2 - Use the periodic table to give the name and symbol...Ch. 2 - Use the periodic table to give the name and symbol...Ch. 2 - Write a symbol for each of the following neutral...Ch. 2 - Write a symbol for each of the following neutral...Ch. 2 - Using the periodic table, predict whether the...Ch. 2 - Using the periodic table, predict whether the...Ch. 2 - For each of the following compounds, state whether...Ch. 2 - For each of the following compounds, state whether...Ch. 2 - For each of the following pairs of ions, write the...Ch. 2 - For each of the following pairs of ions, write the...Ch. 2 - Name the following compounds: CsCl BaO K2S BeCl2...Ch. 2 - Name the following compounds: NaF Rb2O BCl3 H2Se...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Each of the following compounds contains a metal...Ch. 2 - Each of the following compounds contains a metal...Ch. 2 - The following ionic compounds are found in common...Ch. 2 - The following ionic compounds are found in common...Ch. 2 - What are the IUPAC names of the following...
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