Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 2, Problem 42E
Use the periodic table to give the name and symbol for each of the following elements:
- the halogen in the same period as the alkali metal with 11 protons
- the alkaline earth metal in the same period with the neutral noble gas with 18 electrons
- the noble gas in the same row as an isotope with 30 neutrons and 25 protons
- the noble gas in the same period as gold
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 2 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 2 - In the following drawing, the green spheres...Ch. 2 - Which postulate of Dalton’s theory is consistent...Ch. 2 - Identify the postulate of Dalton’s theory that is...Ch. 2 - Samples of compound X, Y, and Z are analyzed, with...Ch. 2 - The existence of isotopes violates one of the...Ch. 2 - How are electrons and protons similar? How are...Ch. 2 - How are protons and neutrons similar? How are they...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - In what way are isotopes of a given element always...
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