Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 2, Problem 12E
Write the symbol for each of the following ions:
- the ion with a 3+ charge, 28 electrons, and a mass number of 71
- the ion with 36 electrons, 35 protons, and 45 neutrons
- the ion with 86 electrons, 142 neutrons, and a 4+ charge
- the ion with a 2+ charge,
atomic number 38, and mass number 87
Expert Solution & Answer
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 2 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 2 - In the following drawing, the green spheres...Ch. 2 - Which postulate of Dalton’s theory is consistent...Ch. 2 - Identify the postulate of Dalton’s theory that is...Ch. 2 - Samples of compound X, Y, and Z are analyzed, with...Ch. 2 - The existence of isotopes violates one of the...Ch. 2 - How are electrons and protons similar? How are...Ch. 2 - How are protons and neutrons similar? How are they...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - In what way are isotopes of a given element always...
Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - The following are properties of isotopes of two...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Click on the site...Ch. 2 - Click on the site...Ch. 2 - An element has the following natural abundances...Ch. 2 - Average atomic masses listed by JUPAC are based on...Ch. 2 - Variations in average atomic mass may be observed...Ch. 2 - The average atomic masses of some elements may...Ch. 2 - The 18O:16O abundance ratio in some meteorites is...Ch. 2 - Explain why the symbol for an atom of the element...Ch. 2 - Explain why the symbol for the element sulfur and...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Write the empirical formulas for the following...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Using the periodic table, classify each of the...Ch. 2 - Using the periodic table, classify each of the...Ch. 2 - Using the periodic table, Identify the lightest...Ch. 2 - Using the periodic table, Identify the heaviest...Ch. 2 - Use the periodic table to give the name and symbol...Ch. 2 - Use the periodic table to give the name and symbol...Ch. 2 - Write a symbol for each of the following neutral...Ch. 2 - Write a symbol for each of the following neutral...Ch. 2 - Using the periodic table, predict whether the...Ch. 2 - Using the periodic table, predict whether the...Ch. 2 - For each of the following compounds, state whether...Ch. 2 - For each of the following compounds, state whether...Ch. 2 - For each of the following pairs of ions, write the...Ch. 2 - For each of the following pairs of ions, write the...Ch. 2 - Name the following compounds: CsCl BaO K2S BeCl2...Ch. 2 - Name the following compounds: NaF Rb2O BCl3 H2Se...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Write the formulas of the following compounds:...Ch. 2 - Each of the following compounds contains a metal...Ch. 2 - Each of the following compounds contains a metal...Ch. 2 - The following ionic compounds are found in common...Ch. 2 - The following ionic compounds are found in common...Ch. 2 - What are the IUPAC names of the following...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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