(a)
Interpretation: Whether the given change is physical or chemical needs to be identified.
The copper wire is bent.
Concept Introduction: When a substance changes its appearance or change in the state takes place and there is no change in its chemical composition, the change is said to be physical. On the other hand, when there is a change in the chemical composition of a substance or a new substance is formed after a
Physical change.
When a copper wire is bent, its physical appearance changes. There is no change in the chemical property of the copper wire. The chemical composition remains the same and no new compound is formed. Thus, when the copper wire is bent it is a physical change.
(b)
Interpretation: Whether the given change is physical or chemical needs to be identified.
Burning of charcoal.
Concept Introduction: When a substance changes its appearance or change in the state takes place and there is no change in its chemical composition, the change is said to be physical. On the other hand, when there is a change in the chemical composition of a substance or a new substance is formed after a chemical reaction, it is known as a chemical change.
Chemical change.
Burning of charcoal in a grill changes the chemical properties of charcoal. Due to combustion, it gets oxidized. Also, a combustion reaction is involved, thus, it is a chemical change.
Thus, the burning of charcoal in a grill is a chemical change. Here, the heat involved in combustion is a clue for chemical change.
(c)
Interpretation: Whether the given change is physical or chemical needs to be identified.
Rise in bread dough after addition of yeast
Concept Introduction: When a substance changes its appearance or change in the state takes place and there is no change in its chemical composition, the change is said to be physical. On the other hand, when there is a change in the chemical composition of a substance or a new substance is formed after a chemical reaction, it is known as a chemical change.
Chemical change.
The rise in bread dough when yeast is added is a chemical change. The reaction is known as fermentation. In this reaction, carbohydrate is consumed and carbon dioxide gas is released. This causes rises in the dough. The reaction is irreversible and it is a chemical change.
Here, a change in the shape of dough that cannot be reversed is a clue for a chemical change.
(d)
Interpretation: Whether the given change is physical or chemical needs to be identified.
Sugar is dissolved in water.
Concept Introduction: When a substance changes its appearance or change in the state takes place and there is no change in its chemical composition, the change is said to be physical. On the other hand, when there is a change in the chemical composition of a substance or a new substance is formed after a chemical reaction, it is known as a chemical change.
Physical change.
When sugar is dissolved in water, no change in the chemical composition of water takes place. Also, the process is reversible. As no new substance is formed, it is a physical change.
Chapter 2 Solutions
EP CHEMISTRY-ETEXT ACCESS
- 3. a. Use the MS to propose at least two possible molecular formulas. For an unknown compound: 101. 27.0 29.0 41.0 50.0 52.0 55.0 57.0 100 57.5 58.0 58.5 62.0 63.0 64.0 65.0 74.0 40 75.0 76.0 20 20 40 60 80 100 120 140 160 180 200 220 m/z 99.5 68564810898409581251883040 115.0 116.0 77404799 17417M 117.0 12.9 118.0 33.5 119.0 36 133 0 1.2 157.0 2.1 159.0 16 169.0 219 170.0 17 171.0 21.6 172.0 17 181.0 1.3 183.0 197.0 100.0 198.0 200. 784 Relative Intensity 2 2 8 ō (ppm) 6 2arrow_forwardSolve the structure and assign each of the following spectra (IR and C-NMR)arrow_forward1. For an unknown compound with a molecular formula of C8H100: a. What is the DU? (show your work) b. Solve the structure and assign each of the following spectra. 8 6 2 ō (ppm) 4 2 0 200 150 100 50 ō (ppm) LOD D 4000 3000 2000 1500 1000 500 HAVENUMBERI -11arrow_forward
- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
- Label the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forward
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