Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.76E
Which one of the following substances is a chemical compound?
a. blood
b. water
c. oxygen
d. air
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Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
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Chapter 2 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 2 - Draw a formula for each of the following molecules...Ch. 2 - Prob. 2.2ECh. 2 - Write formulas for the following molecules using...Ch. 2 - Write formulas for the following molecules using...Ch. 2 - Determine the number of each type of atom in...Ch. 2 - Determine the number of each type of atom in...Ch. 2 - Tell what is wrong with each of the following...Ch. 2 - Tell what is wrong with each of the following...Ch. 2 - Prob. 2.9ECh. 2 - Prob. 2.10E
Ch. 2 - Determine the number of electrons that would have...Ch. 2 - Determine the number of electrons that would have...Ch. 2 - Determine the number of electrons and protons...Ch. 2 - Determine the number of electrons and protons...Ch. 2 - Prob. 2.15ECh. 2 - Prob. 2.16ECh. 2 - Write symbols like those given in Exercises 2.15...Ch. 2 - Write symbols like those given in Exercises 2.15...Ch. 2 - Prob. 2.19ECh. 2 - Prob. 2.20ECh. 2 - Write isotope symbols for neutral atoms with the...Ch. 2 - Write isotope symbols for neutral atoms with the...Ch. 2 - Write the symbols and names for two elements whose...Ch. 2 - Round atomic weights to the nearest whole number,...Ch. 2 - Round atomic weights to the nearest whole number,...Ch. 2 - What are the symbol and name for an element whose...Ch. 2 - In the first 36 elements, 6 elements have atoms...Ch. 2 - What are the symbol and name of the element whose...Ch. 2 - Prob. 2.29ECh. 2 - Prob. 2.30ECh. 2 - The molecular weight was determined for a gas that...Ch. 2 - A flammable gas is known to contain only carbon...Ch. 2 - Glycine, an amino acid found in proteins, has a...Ch. 2 - Serine, an amino acid found in proteins, has a...Ch. 2 - Naturally occurring sodium has a single isotope....Ch. 2 - Naturally occurring aluminum has a single isotope....Ch. 2 - Calculate the atomic weight of lithium on the...Ch. 2 - Calculate the atomic weight of boron on the basis...Ch. 2 - Calculate the atomic weight of silicon on the...Ch. 2 - Calculate the atomic weight of copper on the basis...Ch. 2 - Refer to the periodic table and determine how many...Ch. 2 - Refer to the periodic table and determine how many...Ch. 2 - Write three relationships equalities based on the...Ch. 2 - Write three relationships equalities based on the...Ch. 2 - Use a factor derived from the relationships...Ch. 2 - Use a factor derived from the relationships...Ch. 2 - Prob. 2.47ECh. 2 - Refer to the periodic table and calculate the...Ch. 2 - Prob. 2.49ECh. 2 - Prob. 2.50ECh. 2 - Answer the following questions based on the...Ch. 2 - Answer the following questions based on...Ch. 2 - How many moles of N2O5 contain the same number of...Ch. 2 - How many grams of C2H6O contain the same number of...Ch. 2 - Prob. 2.55ECh. 2 - Determine the mass percentage of hydrogen in CH4...Ch. 2 - Prob. 2.57ECh. 2 - Prob. 2.58ECh. 2 - Urea (CH4N2O) and ammonium sulfate (N2H8SO4) are...Ch. 2 - Prob. 2.60ECh. 2 - Prob. 2.61ECh. 2 - Prob. 2.62ECh. 2 - Prob. 2.63ECh. 2 - The mass of a single carbon 12 atom is 1.991023g....Ch. 2 - Prob. 2.65ECh. 2 - Prob. 2.66ECh. 2 - a. Explain how atoms of different elements differ...Ch. 2 - The atomic weight of aluminum is 26.98u and the...Ch. 2 - Answer the question in the caption of Figure 2.3...Ch. 2 - Answer the question in the caption of Figure 2.5...Ch. 2 - Prob. 2.71ECh. 2 - Prob. 2.72ECh. 2 - Prob. 2.73ECh. 2 - Prob. 2.74ECh. 2 - Prob. 2.75ECh. 2 - Which one of the following substances is a...Ch. 2 - Which of the following is true about compounds?...Ch. 2 - C1734l has a.17 protons, 17 electrons, and 17...Ch. 2 - If two atoms are isotopes, they will a.have same...Ch. 2 - Copper (Cu) has an atomic number of 29 and a mass...Ch. 2 - Atoms are electrically neutral. This means that an...Ch. 2 - The negative charged particle found within the...Ch. 2 - Prob. 2.83ECh. 2 - Prob. 2.84ECh. 2 - The mass of an atom is almost entirely contributed...Ch. 2 - Which of the following is the chemical symbol for...Ch. 2 - Prob. 2.87ECh. 2 - What is the mass number of an atom with 60...Ch. 2 - Which of the following represents Avogadros...Ch. 2 - Which of the following has the greatest number of...Ch. 2 - The formula of carbon dioxide is CO2. Its...Ch. 2 - What is the molar mass of calcium oxide, CaO? a....Ch. 2 - How many grams are contained in 0.200mol of...Ch. 2 - How many moles are contained in a 54.0g sample of...
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