The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted. Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

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Answer 1

Question

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

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Answer 3

Question

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

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Answer 4

Question

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

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Answer 5

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 6

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 7

Chapter 19.16, Problem 19.23P

(a)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

Concept introduction:

The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. The hydrogen atoms present on ammonia can be replaced with an alkyl or aryl group. Amines can act as bases and nucleophiles due to the unshared electron pair.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains the products from the reactions of the given amines with sodium nitrite in dilute HCl are to be predicted.

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Chapter 19 Solutions