The conversion of benzoic acid to benzylamine by using reductive amination is to be shown. Concept introduction: Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 1

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 3

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 4

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 5

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 6

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 7

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

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