To propose: The mechanism for the given reaction. Interpretation: The mechanism for the given reaction is to be proposed. Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines . Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 1

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Arrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidity

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Answer 2

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 3

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 4

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 5

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 6

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 7

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 8

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 9

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 10

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 11

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author proposes the mechanism for the given reaction.

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Chapter 19 Solutions