The synthesis of the given compound using direct alkylation is to be stated. Concept introduction: Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

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Answer 1

Question

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

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1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br O

Answer 2

Question

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

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Answer 3

Question

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

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Answer 4

Question

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

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Answer 5

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 6

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 7

Chapter 19.11, Problem 19.16P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given compound using direct alkylation is to be stated.

Concept introduction:

Amine alkylation is the reaction in which an alkyl halide reacts with ammonia or an amine. This is a type of nucleophilic aliphatic substitution. Exhaustive alkylation of an amine leads to the successive substitution of a hydrogen by an alkyl group and the formation of quaternary ammonium salt takes place.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

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