Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 19, Problem 9E
Why is the formation of slag useful during the smelting of iron?
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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label
each compound as chiral or achiral.
OH
HO
CI
Br
H
CI
CI
Br
CI
CI
Xf x f g
Br
D
OH
Br
Br
H₂N
R.
IN
Ill
I
-N
S
OMe
D
II
H
CO₂H
1/111
DuckDuckG
These are synthesis questions. You need to show how the starting material can be converted into
the product(s) shown. You may use any reactions we have learned. Show all the reagents you
need. Show each molecule synthesized along the way and be sure to pay attention to the
regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made
along the way, you need to draw both enantiomers and label the mixture as "racemic".
All of the carbon atoms of the products must come from the starting material!
?
H
H
Q5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show
stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship
between each pair of the stereoisomers you have drawn.
Chapter 19 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 19 - Write the electron configurations far each of the...Ch. 19 - Write the electron con?gurations for each of the...Ch. 19 - Write the electron configurations for each of the...Ch. 19 - Why are the lanthanoid elements not found in...Ch. 19 - Which of the following elements is most likely to...Ch. 19 - Which of the following is the strongest oxidizing...Ch. 19 - Which of the following elements is most likely to...Ch. 19 - The following reactions all occur in a blast...Ch. 19 - Why is the formation of slag useful during the...Ch. 19 - Would you expect an aqueous manganese (VII) oxide...
Ch. 19 - Iron (II) can be oxidized to iron (III) by...Ch. 19 - How many cubic feet of air at a pressure of 760...Ch. 19 - Find the potentials of the following...Ch. 19 - A 2.5624-g sample of a pure solid alkali metal...Ch. 19 - The standard reduction potential for the reaction...Ch. 19 - Predict the products of each of the following...Ch. 19 - Predict the products of each of the following...Ch. 19 - Describe the electrolytic process for refining...Ch. 19 - Predict the products of the following reactions...Ch. 19 - What is the gas produced when iron(II) sulfide is...Ch. 19 - Predict the products of each of the following...Ch. 19 - Balance the following equations by...Ch. 19 - Dilute sodium cyanide solution is slowly dripped...Ch. 19 - Predict which will be more stable, [CrO4]2- or...Ch. 19 - Give the oxidation state of the metal for each of...Ch. 19 - Indicate the coordination number for the central...Ch. 19 - Give the coordination numbers and write the...Ch. 19 - Give the coordination number for each metal ion in...Ch. 19 - Sketch the structures of the following complexes....Ch. 19 - Draw diagrams for any Cis, trans, and optical...Ch. 19 - Name each of the compounds or ions given in...Ch. 19 - Name each of the compounds or ions given in...Ch. 19 - Specify whether the following complexes have...Ch. 19 - Predict whether the carbonate ligand CO32- will...Ch. 19 - Draw the geometric, linkage, and ionization...Ch. 19 - Determine the number of unpaired electrons...Ch. 19 - Draw the Crystal field diagrams for [Fe(NO2)6]4-...Ch. 19 - Give the oxidation state of the metal, number of d...Ch. 19 - The solid anhydrous solid CoCl2 is blue in color....Ch. 19 - Is it possible for a complex of a metal in the...Ch. 19 - How many unpaired electrons are present in each of...Ch. 19 - Explain how the diphosphate ion, [O3P-O-PO3]4-,...Ch. 19 - For complexes of the same metal ion with no change...Ch. 19 - Trimethylphosphine, P(CH3)3, can act as a ligand...Ch. 19 - Would you expect the complex [Co(en)3]Cl3 to have...Ch. 19 - Would you expect the Mg3[Cr(CN)5]2 to be...Ch. 19 - Would you expect salts of the gold(I) ion, Au+, to...Ch. 19 - [CuCl4]2- is green. [Cu(H2O)6]2+ is blue. Which...
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- Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forwardNonearrow_forwardQ4: Comparing (3S,4S)-3,4-dimethylhexane and (3R,4S)-3,4-dimethylhexane, which one is optically active? Briefly explain.arrow_forward
- Nonearrow_forwardNonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forward
- Determine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward
- = +92kJ ΔΗ = +170kJ Use the following reactions: 2NH3(9) N2(g) + 3H2(g) → 11/N2(g) + 2H2O (1) → NO2(g) + 2H2(g) Determine the DH° of this reaction: NO2(g) + H2(g) → 2(g) → 2H2O(l) + NH3(9) ΔΗarrow_forwardDetermine the entropy change for the reaction SO2(g) + O2(g) following information: Standard Entropy Values of Various Substance Substance SO2(g) 02(g) SO3(g) So (J/mol K) 248.2 205.0 256.8 → SO3(g) given thearrow_forwardIndicate which one of the following reactions most certainly results in a negative AS sys. O1402(g) + 3NH4NO3 (s) + C10 H22(1) → 3N2(g) + 17H2O(g) + 10CO2(g) ○ CO2(aq) = CO2(g) ○ H₂O(g) = H₂O(s) CaCO3(g) = CaO(s) + CO2(g) O CuSO4.5H2O(s) = CuSO4(s) + 5H2O(g)arrow_forward
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