1st Edition

ISBN: 9781938168390

Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher: OpenStax

Concept explainers

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Textbook Question

Chapter 19, Problem 29E

Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers..

(a) [Pt(H₂O)₂Br₂] (square planar).

(b) [Pt(NH₃)(py)(Cl)(Br)] (square planar, py = pyridine, C₅H₅N).

(d) [Pt(NH₃)₃Cl]⁺ (square planar).

(e) [Ni(H₂O)₄Cl₂].

(f) [Co(C₂O₄)2Cl₂]3- (note that C₂O₄²- is the bidentate oxalate ion, -O₂CCO₃^-)

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Chapter 19, Problem 28E

Chapter 19, Problem 30E

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Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers.(a) [Pt(H2O)2Br2] (square planar)(b) [Pt(NH3)(py)(Cl)(Br)] (square planar, py = pyridine, C5H5N)(c) [Zn(NH3)3Cl]+ (tetrahedral)(d) [Pt(NH3)3Cl]+ (square planar)(e) [Ni(H2O)4Cl2](f) [Co(C2O4)2Cl2]3− (note that C2O42− is the bidentate oxalate ion, −O2CCO2−)

Chapter 19 Solutions

Chemistry by OpenStax (2015-05-04)

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