Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 19, Problem 35E
Draw the geometric, linkage, and ionization isomers for [COCl5CN][CN].
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
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10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
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20
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-35
-1.0
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0.5
ppm
3.5
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2.5
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1.5
1.0
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ppm
Show work with explanation. don't give Ai generated solution
Chapter 19 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 19 - Write the electron configurations far each of the...Ch. 19 - Write the electron con?gurations for each of the...Ch. 19 - Write the electron configurations for each of the...Ch. 19 - Why are the lanthanoid elements not found in...Ch. 19 - Which of the following elements is most likely to...Ch. 19 - Which of the following is the strongest oxidizing...Ch. 19 - Which of the following elements is most likely to...Ch. 19 - The following reactions all occur in a blast...Ch. 19 - Why is the formation of slag useful during the...Ch. 19 - Would you expect an aqueous manganese (VII) oxide...
Ch. 19 - Iron (II) can be oxidized to iron (III) by...Ch. 19 - How many cubic feet of air at a pressure of 760...Ch. 19 - Find the potentials of the following...Ch. 19 - A 2.5624-g sample of a pure solid alkali metal...Ch. 19 - The standard reduction potential for the reaction...Ch. 19 - Predict the products of each of the following...Ch. 19 - Predict the products of each of the following...Ch. 19 - Describe the electrolytic process for refining...Ch. 19 - Predict the products of the following reactions...Ch. 19 - What is the gas produced when iron(II) sulfide is...Ch. 19 - Predict the products of each of the following...Ch. 19 - Balance the following equations by...Ch. 19 - Dilute sodium cyanide solution is slowly dripped...Ch. 19 - Predict which will be more stable, [CrO4]2- or...Ch. 19 - Give the oxidation state of the metal for each of...Ch. 19 - Indicate the coordination number for the central...Ch. 19 - Give the coordination numbers and write the...Ch. 19 - Give the coordination number for each metal ion in...Ch. 19 - Sketch the structures of the following complexes....Ch. 19 - Draw diagrams for any Cis, trans, and optical...Ch. 19 - Name each of the compounds or ions given in...Ch. 19 - Name each of the compounds or ions given in...Ch. 19 - Specify whether the following complexes have...Ch. 19 - Predict whether the carbonate ligand CO32- will...Ch. 19 - Draw the geometric, linkage, and ionization...Ch. 19 - Determine the number of unpaired electrons...Ch. 19 - Draw the Crystal field diagrams for [Fe(NO2)6]4-...Ch. 19 - Give the oxidation state of the metal, number of d...Ch. 19 - The solid anhydrous solid CoCl2 is blue in color....Ch. 19 - Is it possible for a complex of a metal in the...Ch. 19 - How many unpaired electrons are present in each of...Ch. 19 - Explain how the diphosphate ion, [O3P-O-PO3]4-,...Ch. 19 - For complexes of the same metal ion with no change...Ch. 19 - Trimethylphosphine, P(CH3)3, can act as a ligand...Ch. 19 - Would you expect the complex [Co(en)3]Cl3 to have...Ch. 19 - Would you expect the Mg3[Cr(CN)5]2 to be...Ch. 19 - Would you expect salts of the gold(I) ion, Au+, to...Ch. 19 - [CuCl4]2- is green. [Cu(H2O)6]2+ is blue. Which...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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