The labeled carbon in pyruvate should be determined when it is comes from glucose-1- 14 C Glycolysis cycle: In the carbohydrate metabolism , the conversion of glucose into pyruvate is known as Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate, In this process, the carbons atoms numbered in the order of where it is in glucose,

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Answer 1

Question

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.

Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

Answer 2

Question

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

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Answer 3

Question

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 6

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 7

Chapter 19, Problem 41P

(a)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-1-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle, the glucose is converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 8

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 9

(b)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-2-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 10

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 11

(c)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-3-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 12

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 13

(d)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-4-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 14

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 15

(e)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-5-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 16

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 17

(f)

Interpretation Introduction

Interpretation:

The labeled carbon in pyruvate should be determined when it is comes from glucose-6-14C

Glycolysis cycle:

In the carbohydrate metabolism, the conversion of glucose into pyruvate is known as

Glycolysis cycle. In this cycle the glucose converted into D-glyceraldehye-3-phosphate and this D-glyceraldehye-3-phosphate is further converted into pyruvate,

In this process, the carbons atoms numbered in the order of where it is in glucose,

Answer 18

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Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 19.4 - Prob. 1P Ch. 19.4 - How many molecules of NADH are formed from the...Ch. 19.4 - Why does the OH group add to the -carbon rather...Ch. 19.5 - Prob. 4P Ch. 19.5 - Prob. 5P Ch. 19.5 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 19.5 - Prob. 7P Ch. 19.6 - Prob. 8P Ch. 19.6 - Prob. 9P Ch. 19.6 - Propose a mechanism for the reduction of...

Solution Summary: The author explains that in the carbohydrate metabolism, the conversion of glucose into pyruvate is known as Glycolysis cycle.

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Chapter 19 Solutions