Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Chapter 19, Problem 3P
Interpretation Introduction

Interpretation:

The difference in structure between an aldose and a ketose and between an aldopentose and a ketopentose should be determined.

Concept introduction:

Carbohydrates means hydrate of carbon, they have the general formula Cm(H2O)n (m and n can be same or different). For example: the formula of Glucose is C6 H12 O6, which can alternatively be written as C6 (H2 O)6.

At the molecular level, carbohydrates are polyhydroxy aldehydes and polyhydroxy ketones.

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H- H H H H H H Identify and select all structures below that represent a constitutional isomer(s) of the compound shown above. H- H H H A. H H H H-C CI H H D. H H H H H H C C -H H C C H H H H B. H CI H H- C C H H H H E. H CI H C.
Why doesn't this carry on to form a ring by deprotonating the alpha carbon and the negatively-charged carbon attacking the C=O?
6. A solution (0.0004 M) of Fe(S2CNEt2)3 (see the structural drawing below) in chloroform has absorption bands at: 350 nm (absorbance A = 2.34); 514 nm(absorbance A = 0.0532); Calculate the molar absorptivity values for these bands. Comment on their possible nature (charge transfer transitions or d-d S N- transitions?). (4 points)

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Introduction to General, Organic and Biochemistry

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