Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
Book Icon
Chapter 19, Problem 32P

(a)

Interpretation Introduction

Interpretation:

Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.

Concept Introduction:

Cope elimination:

When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.

The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.

(b)

Interpretation Introduction

Interpretation:

Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.

Concept Introduction:

Cope elimination:

When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.

The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.

(c)

Interpretation Introduction

Interpretation:

Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.

Concept Introduction:

Cope elimination:

When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.

The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.

(d)

Interpretation Introduction

Interpretation:

Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.

Concept Introduction:

Cope elimination:

When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.

The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.

Blurred answer
Students have asked these similar questions
this is an organic chemistry question please answer accordindly!! please post the solution draw the figures and post, answer the question in a very simple and straight forward manner thanks!!!!! please answer EACH part till the end and dont just provide wordy explanations wherever asked for structures or diagrams, please draw them on a paper and post clearly!! answer the full question with all details EACH PART CLEARLY please thanks!! im reposting this kindly solve all parts and draw it not just word explanations!!
Please correct answer and don't used hand raiting
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Select to Edit Arrows H H Select to Add Arrows > H CFCI: Select to Edit Arrows H Select to Edit Arrows

Chapter 19 Solutions

Organic Chemistry (8th Edition)

Knowledge Booster
Background pattern image
Recommended textbooks for you
  • Text book image
    Introduction to General, Organic and Biochemistry
    Chemistry
    ISBN:9781285869759
    Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning