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Name the following:
(a)
Interpretation:
The given chemical structure has to be named.
Concept Introduction:
The nomenclature of the chemical structures:
A molecular formula describes the total number and types of the atoms in a molecule, whereas chemical structures describe the arrangement of atoms in a compound.
International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. IUPAC names are totally different from common names because IUPAC names are applied at international level and it comprises suffix, prefix, numbers and other priority rules. The numbering starts from the side of substituent; if more than one substituent groups are present then these are cited alphabetically in the compound’s name.
Answer to Problem 21P
The name of the given compound is
Explanation of Solution
The structure of the given compound is shown below.
Figure 1
The compounds that comprise the saturated four membered rings are named as azetidines. The methyl substituent is present at the second carbon atom. Therefore, the name of the compound shown in figure is
(b)
Interpretation: The given chemical structure has to be named.
Concept Introduction:
The nomenclature of the chemical structures:
A molecular formula describes the total number and types of the atoms in a molecule, whereas chemical structures describe the arrangement of atoms in a compound.
International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. IUPAC names are totally different from common names because IUPAC names are applied at international level and it comprises suffix, prefix, numbers and other priority rules. The numbering starts from the side of substituent; if more than one substituent groups are present then these are cited alphabetically in the compound’s name.
Answer to Problem 21P
The name of the given compound is
Explanation of Solution
The structure of the given compound is shown below.
Figure 2
The compounds that comprise the saturated six membered rings with a nitrogen atom are named as piperidines. The methyl substituents are present at the second and third carbon atoms. Therefore, the name of the compound shown in figure 2 is
(c)
Interpretation: The given chemical structure has to be named.
Concept Introduction:
The nomenclature of the chemical structures:
A molecular formula describes the total number and types of the atoms in a molecule, whereas chemical structures describe the arrangement of atoms in a compound.
International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. IUPAC names are totally different from common names because IUPAC names are applied at international level and it comprises suffix, prefix, numbers and other priority rules. The numbering starts from the side of substituent; if more than one substituent groups are present then these are cited alphabetically in the compound’s name.
Answer to Problem 21P
The name of the given compound is
Explanation of Solution
The structure of the given compound is shown below.
Figure 3
The compounds that comprise the unsaturated four membered rings with a nitrogen atom are named as pyrroles. The chlorine substituent is present at the third carbon atom. Therefore, the name of the compound shown in figure 3 is
(d)
Interpretation:
The given chemical structure has to be named.
Concept Introduction:
The nomenclature of the chemical structures:
A molecular formula describes the total number and types of the atoms in a molecule, whereas chemical structures describe the arrangement of atoms in a compound.
International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. IUPAC names are totally different from common names because IUPAC names are applied at international level and it comprises suffix, prefix, numbers and other priority rules. The numbering starts from the side of substituent; if more than one substituent groups are present then these are cited alphabetically in the compound’s name.
Answer to Problem 21P
The name of the given compound is
Explanation of Solution
The structure of the given compound is shown below.
Figure 4
The compounds that comprise saturated six membered rings with a nitrogen atom are named as piperidines. The ethyl and methyl substituents are present at the second and fifth carbon atoms respectively. Therefore, the name of the compound shown in figure is
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Chapter 19 Solutions
Organic Chemistry (8th Edition)
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- How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom moleculearrow_forwardIn the drawing area below, draw the major products of this organic reaction: 1. NaOH ? 2. CH3Br If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. No reaction. Click and drag to start drawing a structure. ☐ : A คarrow_forwardPredict the major products of the following organic reaction: NC Δ ? Some important Notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to draw bonds carefully to show important geometric relationships between substituents. Note: if your answer contains a complicated ring structure, you must use one of the molecular fragment stamps (available in the menu at right) to enter the ring structure. You can add any substituents using the pencil tool in the usual way. Click and drag to start drawing a structure. Х аarrow_forward
- Predict the major products of this organic reaction. Be sure you use dash and wedge bonds to show stereochemistry where it's important. + ☑ OH 1. TsCl, py .... 文 P 2. t-BuO K Click and drag to start drawing a structure.arrow_forwardConsider this organic reaction: ( Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. Click and drag to start drawing a structure. Х : а ค 1arrow_forwardIn the drawing area below, draw the major products of this organic reaction: If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. 1. NaH 2. CH3Br ? Click and drag to start drawing a structure. No reaction. : ☐ Narrow_forward
- + Predict the major product of the following reaction. : ☐ + ☑ ค OH H₂SO4 Click and drag to start drawing a structure.arrow_forwardConsider this organic reaction: ... OH CI Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. ☐ No Reaction. Click and drag to start drawing a structure. : аarrow_forwardConsider the following reactants: Br Would elimination take place at a significant rate between these reactants? Note for advanced students: by significant, we mean that the rate of elimination would be greater than the rate of competing substitution reactions. yes O no If you said elimination would take place, draw the major products in the upper drawing area. If you said elimination would take place, also draw the complete mechanism for one of the major products in the lower drawing area. If there is more than one major product, you may draw the mechanism that leads to any of them. Major Products:arrow_forward
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