The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given. Concept Introduction: The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check CF3 (Choose one) OH (Choose one) H (Choose one) (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy

Identifying electron-donating and electron-withdrawing effects For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density CF3 O donating O donating O electron-rich O withdrawing withdrawing O no inductive effects O no resonance effects O electron-deficient O similar to benzene OCH3 Explanation Check O donating O donating ○ withdrawing withdrawing O no inductive effects no resonance effects electron-rich electron-deficient O similar to benzene Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center

The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Answer 6

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

Answer 7

Chapter 19, Problem 40P

(a)

Interpretation Introduction

Interpretation:

The product obtained in the reaction of 3-acetylfuran with nitric acid and sulfuric acid has to be given.

Concept Introduction:

The reaction of sulfuric acid and nitric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant. The nucleophilicity of the carbon atoms present in the furan depends upon the nature of substituents attached to it.

Answer 8

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

Answer 9

(b)

Interpretation Introduction

Interpretation: The product formed in the reaction of 2-nitrothiophene with bromine has to be given.

Concept Introduction:

The reaction of bromine with alkyl and aryl groups is a type of electrophilic substitution reaction in which Br+ ion attacks as electrophile. The nucleophilicity of the carbon atoms present in the thiophene depends upon the nature of substituents attached to it.

Answer 10

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

Answer 11

(c)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 4-dimethylaminepyridine with methyl iodide has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

Answer 12

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyridione with PCl3 has to be given.

Concept Introduction:

Phosphorus trichloride reacts with hydroxyl group and leads to the formation of HPOCl2 and chloride substituted alkyl group. This is a type of substitution reaction in which bromine atom substitute’s hydroxyl atom present in the molecule.

Answer 14

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

Answer 15

(e)

Interpretation Introduction

Interpretation: The product obtained in the reaction of 1,4-dimethylpyridine hydroxide with formic acid and hydrochloric acid has to be given.

Concept Introduction:

Tertiary amines exist as quaternary ammonium salts in the electrolytic solution. Quaternary ammonium salts are the salts of nitrogen in which four groups are attached to nitrogen and it exhibits a positive charge which is stabilized by the negative charges present in the solution.

Answer 16

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Answer 17

(f)

Interpretation Introduction

Interpretation: The product obtained in the reaction of pyrrole with CH3CH2MgBr has to be given.

Concept Introduction:

The alkyl group attached to magnesium bromide acts as a nucleophile because carbon atom is more electronegative as compared to magnesium due to which carbon atom exhibits partial negative charge in the reaction of Grignard reagent.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 21

Ch. 19.1 - Name the following:Ch. 19.2 - Prob. 3P Ch. 19.2 - Prob. 4P Ch. 19.3 - Draw the product of each of the following...Ch. 19.5 - Prob. 6P Ch. 19.5 - Explain why cyclopentadiene (pKa = 15) is more...Ch. 19.5 - When pyrrole is added to a dilute solution of...Ch. 19.6 - Prob. 10P Ch. 19.6 - How to the mechanisms of the following reactions...Ch. 19.6 - Prob. 12P

Solution Summary: The author explains the reaction of 3-acetylfuran with nitric acid and sulfuric acid results in the generation of nitronium ion which attacks the most nucleophilic position of the reactant

Want to see the full answer?

Chapter 19 Solutions