ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 19, Problem 30P
Interpretation Introduction

Interpretation:

The given points regarding the establishment of equilibrium of aconitic acid with isocitric acid and citric acid respectively in presence of aconitase enzyme are to be explained.

Concept Introduction:

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A compound exhibits anumber of stereoisomers if it contains more than one stereogenic centers.

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The maximum number of stereoisomers of a compound can be calculated using the 2n formula, here n is thenumber of stereogenic centers

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A carbon atom that is associated with four different groups is termeda chiralcenter or stereogeniccenter.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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