ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 19, Problem 16P
Interpretation Introduction

Interpretation:

The synthetic procedures for the preparation of benzoic acid, labeled with 14C by using benzene and the given compounds have to be described.

Concept Introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction.

The reaction of benzene with alkyl halide in the presence of Lewis acid results in the formation of a nucleophilic product.

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.. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+
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