ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 19, Problem 26P
Interpretation Introduction

Interpretation:

The final product with a molecular formula C9H9ClO3 for the given series of reaction is to be stated.

Concept introduction:

Thionyl chloride (SOCl2) can be used to convert carboxylic into acyl chloride. The overall reaction converts poor leaving group, OH, into a good leaving group, Cl.

Lithium aluminum hydride is a strong reducing agent. The reduction of a carboxylic acid by LiAlH4 yields alcohol.

Oxidation reaction involves an increase in the CX bonds (where X usually is oxygen or a halogen atom) or decrease in the CH bonds.

Reduction reaction involves a decrease in the CX bonds (where X usually is oxygen or a halogen atom) or increase in the CH bonds.

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The acid-base indicator HX undergoes the following reaction in a dilute aqueous solution: HX (color 1) H+ + X- (color 2). The following absorbance data were obtained for a 0.00035 M solution of HX in 0.1 M NaOH and 0.1 M HCI. Measurements were made at wavelengths of 450 nm and 620 nm using a 1.0 cm glass cuvette. 450 620 A(460 nm) A(630 nm) 0.1 M NaOH 0.1 M HCI 0.065 0.435 0.895 0.150 In the 0.1M NaOH solution, the indicator will be almost 100% in the X- form, while in 0.1M HCI, the indicator will be nearly 100% protonated (HX). Calculate the acid dissociation constant for the indicator if a pH=5 buffer solution containing a very small amount of indicator exhibits an absorbance of 0.567 at 450 nm and 0.395 at 620 nm (measured in a 1 cm glass cuvette).
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