(a) Interpretation: A diene that would react with Grubbs catalyst to produce the given compound is to be drawn. Concept introduction: An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 1

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS FOR THE MECHANISM!!! THANKS First image: QUESTION 6. I have to show, with ARROWS and STRUCTURES, the mechanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary. I also tried to draw the mechanism, tell me what to change. Please note that its an AMIDE thats formed not an AMINE the nitrogen has ONE hydrogen and one Phenyl-C-Phenyl. I already asked for this mechanism and got as a final product ...-NH2 not whats shown on the picture, thank you Ths second part. QUESTION 3. I just need a way to synthesize the lactone A, I already started please continue from where I left it Second image: I simply need the products, substrates or reagents, thank you

Indicate how to prepare a 10% sodium hydroxide (NaOH) solution to a slightly alkaline pH.

Answer 2

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 3

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 4

Question

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

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Answer 5

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 6

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 7

Chapter 19, Problem 19.63P

Interpretation Introduction

(a)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes are treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called ring-closing metathesis. A ring is formed in the reaction; therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

A diene that would react with Grubbs catalyst to produce the given compound is to be drawn.

Concept introduction:

An alkene metathesis occurs when one or more alkenes is treated with Grubbs catalyst, which contains a Ru=C bond. In the product of an alkene metathesis, the fragments that are joined by a double bond were initially part of a double bond to other fragments in the reactant. These reactions are particularly useful when the reactants are terminal alkenes. When the reaction produces a new ring, it is called a ring-closing metathesis. A ring is formed in the reaction, therefore, two C=C terminal groups in the reactant must be on the same molecule.

Answer 10

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

Solution Summary: The author explains how a diene reacts with Grubbs catalyst to produce the given compound by undoing alkene metathesis.

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Chapter 19 Solutions