(a) Interpretation: Whether the given carbonyl group requires protection is to be determined. Concept introduction: The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

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Answer 1

Question

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Answer 2

Question

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

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Answer 3

Question

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

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Answer 4

Question

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

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Answer 5

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 6

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 7

Chapter 19, Problem 19.47P

Interpretation Introduction

(a)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the given carbonyl group requires protection is to be determined.

Concept introduction:

The protecting groups are used to make the specific functional group temporarily unreactive in a poly-functional group molecule under reaction conditions needed to make modifications in other functional group in the molecule. The protecting group can be removed once the desired reaction is carried out, and the original functional group is restored.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

Solution Summary: The author explains that the carbonyl in the given substrate needs to be protected on the basis of reaction condition.

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Chapter 19 Solutions