Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C ≡ N ) is to be determined. Concept introduction: Nitrile (R-C ≡ N ) can be hydrolyzed to an amide under either acidic or basic condition. The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction

Interpretation:

Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C≡N) is to be determined.

Concept introduction:

Nitrile (R-C≡N) can be hydrolyzed to an amide under either acidic or basic condition.

The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Don't used hand raiting

CS2(g) →CS(g) + S(g) The rate law is Rate = k[CS2] where k = 1.6 × 10−6 s−¹. S What is the concentration of CS2 after 5 hours if the initial concentration is 0.25 M?

CS2(g) → CS(g) + S(g) The rate law is Rate = k [CS2] where k = 1.6 × 10-6 s−1. S Calculate the half-life.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction

Interpretation:

Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C≡N) is to be determined.

Concept introduction:

Nitrile (R-C≡N) can be hydrolyzed to an amide under either acidic or basic condition.

The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction

Interpretation:

Whether the Wolff-Kishner reduction and Clemmensen reduction should be carried out on a ketone or aldehyde that contains the nitrile group (R-C≡N) is to be determined.

Concept introduction:

Nitrile (R-C≡N) can be hydrolyzed to an amide under either acidic or basic condition.

The Wolff-Kishner reduction is carried out in basic condition in water, and Clemmensen reduction is carried out in acidic condition in water.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.3YT

Interpretation Introduction